RESUMO
It is widely recognized that light exhibits a wave-particle duality. However, the explanation for the photonic spin Hall effect (PSHE) primarily relies on the wave nature of light as dictated by Maxwell's Equations. There is a lack of exploration into the particle nature of light in this regard. In this context, we offer a fresh interpretation of the PSHE from the perspective of particle nature of light. For the out-of-plane PSHE, the spin shifts result from the macroscopic manifestation of the conservation of spin-orbital angular momentum of one photon. For the in-plane PSHE, the spin shifts arise from the spread of in-plane wavevector. Based on the wave nature of light, we also obtain the same spin shifts, confirming the consistency of the wave-particle duality of light. Furthermore, we find that the spin shifts of the PSHE are not the overall displacement of photons with the same handedness, but the outcome of coherent superposition among photons of the same handedness. These discoveries further enhance our comprehension of the fundamental nature of the PSHE.
RESUMO
To investigate the effect of the molecular size of alkanes and the cavity size of cyclodextrins (CDs) on the formation of interfacial host-guest inclusion complexes, the interfacial tension (IFT) of CD (α-CD, ß-CD, γ-CD) solutions against oils (hexadecane, dodecylbenzene) was determined by interfacial dilational rheology measurements. The results show that the "space compatibility" between CDs and oil molecules is crucial for the formation of interface host-guest inclusion complexes. Hexadecane with a smaller molecular size can form host-guest inclusion complexes with small cavities of α-CD and ß-CD, dodecylbenzene with a larger molecular size can form interfacial aggregates with the medium-sized cavity of ß-CD easily, and the polycyclic aromatic hydrocarbon molecules in kerosene can form inclusion complexes with the large cavity of γ-CD. The formation of interfacial inclusion complexes leads to lower IFT values, higher interfacial dilational modulus, nonlinear IFT responses to the interface area oscillating, and skin-like films at the oil-water interface. What's more, the phase behavior of Pickering emulsions formed by CDs with different oils is explored, and the phenomena in alkane-CD emulsions are in line with the results in dilatation rheology. The interfacial active host-guest structure in the kerosene-γ-CD system improves the stability of the Pickering emulsion, which results in smaller emulsion droplets. This unique space compatibility characteristic is of great significance for the application of CDs in selective host-guest recognition, sensors, enhanced oil recovery, food industries, and local drug delivery.
RESUMO
To facilitate the manufacturing of the thin-walled components of 2219 aluminum alloy, the quenching-forming-aging (Q-F-A) process has been increasingly utilized. However, natural aging (NA) after quenching significantly affects the cold forming performance of this alloy. In this study, experiments are conducted to investigate the effect of NA time on the cold forming performance of 2219 aluminum alloy. The results indicate that NA can weaken the Portevin-Le Chatelier (PLC) effect, thereby reducing its influence on the cold forming performance of the alloy. The PLC effect becomes indistinct when the aging time reaches 2 years. The yield strength of 2219 aluminum alloy increases monotonically with aging time, while the elongation first increases rapidly and then decreases. After an aging time of 2 years, the yield strength increases by 28.6% from that of newly quenched alloys. The strain hardening index and hardening coefficient indicate that short-term NA (less than 4 days) increases the work hardening rate, while long-term NA reduces it. Microstructural analysis shows that the strengthening effect of NA on 2219 aluminum alloy is mainly due to the growth of G.P. zones and the precipitation of θⳠphases. The NA precipitation behavior can also cause the aggregation of solute atoms and weaken the PLC effect.