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1.
Plant J ; 111(3): 836-848, 2022 08.
Artigo em Inglês | MEDLINE | ID: mdl-35673966

RESUMO

Lilacs (Syringa L.), a group of well-known ornamental and aromatic woody plants, have long been used for gardening, essential oils and medicine purposes in East Asia and Europe. The lack of knowledge about the complete genome of Syringa not only hampers effort to better understand its evolutionary history, but also prevents genome-based functional gene mining that can help in the variety improvement and medicine development. Here, a chromosome-level genome of Syringa oblata is presented, which has a size of 1.12 Gb including 53 944 protein coding genes. Synteny analysis revealed that a recent duplication event and parallel evolution of two subgenomes formed the current karyotype. Evolutionary analysis, transcriptomics and metabolic profiling showed that segment and tandem duplications contributed to scent formation in the woody aromatic species. Moreover, phylogenetic analysis indicated that S. oblata shared a common ancestor with Osmanthus fragrans and Olea europaea approximately 27.61 million years ago (Mya). Biogeographic reconstruction based on a resequenced data set of 26 species suggested that Syringa originated in the northern part of East Asia during the Miocene (approximately 14.73 Mya) and that the five Syringa groups initially formed before the Late Miocene (approximately 9.97 Mya). Furthermore, multidirectional dispersals accompanied by gene introgression among Syringa species from Northern China during the Miocene were detected by biogeographic reconstruction. Taken together, the results showed that complex gene introgression, which occurred during speciation history, greatly contributed to Syringa diversity.


Assuntos
Oleaceae , Syringa , Cromossomos , Oleaceae/genética , Filogenia , Syringa/genética , Transcriptoma
2.
Ecotoxicol Environ Saf ; 260: 115091, 2023 Jul 15.
Artigo em Inglês | MEDLINE | ID: mdl-37267779

RESUMO

Air quality index (AQI) and air pollutants during two typical pollution episodes, and polycyclic aromatic hydrocarbons (PAHs) in fresh snow after each episode in the winter 2019 across Harbin City in northeast China were investigated to explore the co-environmental behaviors. Significantly greater values of AQI and PAHs were found in the more serious atmospheric pollution episode (episode Ⅱ), demonstrating that PAHs in fresh snow is a robust indicator. PM2.5 was the primary air pollutant in both episodes based on PM2.5/PM10 ratios, which might be attributed to fine particulate converted from gas-to-particle process. PM2.5 and 4-ring PAHs significantly positive correlated, indicating that airborne particulate PAHs were co-emitted and co-transported with atmospheric fine particles released from coal combustion and vehicular emission under low temperature and high relative humidity. 3- and 4- rings PAHs were dominant in episode Ⅱ, while 5- and 6- rings PAHs were found the lowest in both episodes. These characteristics reflected that long-range transportation of coal and biomass burning were from the surrounding areas, while vehicle exhausts were mainly from local emissions. Except for the impact of local pollution source emissions, the regional transport could make a greater contribution in a more serious pollution event.


Assuntos
Poluentes Atmosféricos , Poluição do Ar , Hidrocarbonetos Policíclicos Aromáticos , Material Particulado/análise , Hidrocarbonetos Policíclicos Aromáticos/análise , Neve , Monitoramento Ambiental , Poluentes Atmosféricos/análise , China , Emissões de Veículos/análise , Estações do Ano , Carvão Mineral/análise , Poeira , Poluição do Ar/análise
3.
Ecotoxicology ; 30(7): 1354-1365, 2021 Sep.
Artigo em Inglês | MEDLINE | ID: mdl-33544316

RESUMO

Evidence from terrestrial sedimentary heavy metals record is a robust indicator of anthropogenic activity changes. Heavy metals and particle sizes in 210Pb-dated sediment cores extracted from Hulun and Chagan lakes were measured to reconstruct the sediment record and evaluated health risk of heavy metals in the last 150 years in Northeast China. In general, the particle size of Hulun Lake was finer with more contents of clay than Chagan Lake, while the concentrations of most heavy metals in Hulun Lake was lower. Prior to the 1970s, significant positive correlations between most heavy metals and clay, indicating that that they were likely co-transported and both lakes were dominated by natural inputs. The two records showed significant increases in concentrations of heavy metals between 1970s and 1990s, which were associated with recent anthropogenic activities derived from principal component analysis of clay and heavy metals. Specifically, the exploitation of mineral resources and traffic source in the Hulun Lake, and the emissions of pesticides and fertilizers from agricultural activity, and the combustions of coal and fossil fuels from industrial activity in the Chagan Lake. Since 1990s, natural processes was the main source of heavy metals in Hulun Lake due to the environmental protection policy, while emissions of industrial, agricultural and domestic sewage were still the main source in Chagan Lake. Overall carcinogenic risks caused by single heavy metal elements determined for the two lakes were considered to be acceptable. However, Cr was associated with a risk for children across since 1970s which should be paid more attention.


Assuntos
Metais Pesados , Poluentes Químicos da Água , Criança , China , Monitoramento Ambiental , Sedimentos Geológicos , Humanos , Lagos , Metais Pesados/análise , Medição de Risco , Poluentes Químicos da Água/análise
4.
Ecotoxicology ; 30(7): 1315-1324, 2021 Sep.
Artigo em Inglês | MEDLINE | ID: mdl-33064254

RESUMO

Polycyclic aromatic hydrocarbons (PAHs) in an AMS 14C-dated permafrost soil core extracted from continuous permafrost zone were measured to reconstruct the pollution history from the early Holocene (ca. 15480 a BP) and its potential risks under climate changes were evaluated in northeast China. Total PAH concentrations varied from 209 to 2161 ng/g through the core, which were moderately contaminated in the surface but heavily contaminated historically. Factor analysis indicated that volcanic activity, diagenesis from biological precursors and palaeo forest fires were dominant PAH sources, while petroleum emission was identified in the active layer due to the construction of China-Russia oil pipeline. Significant increases in 5-ring, 6-ring and 7 carcinogenic PAHs (p < 0.05) were observed from surface to the interface of the active layer and ice-rich permafrost layer, showing a selective downward migration in the active layer which might be effected by the repetitive cycles of freezing and thawing. Results implied that PAHs in the ice-rich permafrost layer could lead to an unpredictably serious consequence under the further climate warming.


Assuntos
Pergelissolo , Petróleo , Hidrocarbonetos Policíclicos Aromáticos , Poluentes do Solo , China , Monitoramento Ambiental , Poluição Ambiental , Hidrocarbonetos Policíclicos Aromáticos/análise , Hidrocarbonetos Policíclicos Aromáticos/toxicidade , Medição de Risco , Solo , Poluentes do Solo/análise , Poluentes do Solo/toxicidade
5.
Ecotoxicology ; 30(8): 1521-1526, 2021 Oct.
Artigo em Inglês | MEDLINE | ID: mdl-33755844

RESUMO

Biomonitoring provides direct evidence of the bioavailability and accumulation of toxic elements in the environment, and homing pigeons have been proposed as a biomonitor of atmospheric pollution. We evaluated metal concentrations in homing pigeon feather tissue as a biomonitoring tool. We measured cadmium, lead, and mercury concentrations in feathers collected from 5-6-yo homing pigeons from Guangzhou, Beijing, and Harbin, China during 2011, and feathers of 1, 5, and 10-yo homing pigeons collected from Guangzhou, Beijing, and Harbin, China during 2015-16. We compared metal concentrations in feathers between sexes and among ages and evaluated spatio-temporal differences. Correlations between feather metal concentrations and previously evaluated kidney and liver metal concentrations are reported. There were no significant differences in feather metal concentrations between male and female pigeons or among 1, 5, and 10-yo pigeons. Cadmium, lead, and mercury concentrations in feathers of 1-yo pigeons were significantly correlated with concentrations in liver and kidney tissues, although the correlations were not consistent. Spatio-temporal differences in feather metal concentrations suggest the usefulness of feathers in identifying areas of concern and remedial effectiveness. Homing pigeon feather metal concentrations appear to be useful as a screening biomonitoring tool.


Assuntos
Columbidae , Poluentes Ambientais , Animais , China , Monitoramento Ambiental , Poluentes Ambientais/análise , Plumas/química , Feminino , Masculino , Metais
6.
Ecotoxicology ; 27(2): 169-174, 2018 Mar.
Artigo em Inglês | MEDLINE | ID: mdl-29273855

RESUMO

Atmospheric pollution in urban areas is a major worldwide concern with potential adverse impacts on wildlife and humans. Biomonitoring can provide direct evidence of the bioavailability and bioaccumulation of toxic metals in the environment that is not available with mechanical air monitoring. The current study continues our evaluation of the usefulness of homing pigeon lung tissue as a biomonitor of atmospheric pollution. Homing pigeons (1-2, 5-6, and 9-10+ year old (yo)) collected from Guangzhou during 2015 were necropsied and concentrations of cadmium (Cd), lead (Pb), and mercury (Hg) were measured in lung tissue. Lung Cd and Pb concentrations were significantly greater in 9-10+-year-old pigeons compared with those in other age groups, indicating their bioavailability and bioaccumulation. Lung Pb and Cd concentrations measured in 5-yo pigeons collected from Guangzhou during 2015 were significantly lower than concentrations reported in 5-yo homing pigeons collected from Guangzhou during 2011 and correlated with concentrations measured using mechanical air monitoring. In addition to temporal differences, spatial differences in concentrations of Cd, Pb, and Hg reported in ambient air samples and in pigeon lung tissues collected from Beijing and Guangzhou are discussed.


Assuntos
Poluentes Atmosféricos/metabolismo , Columbidae/metabolismo , Monitoramento Ambiental/métodos , Poluentes Ambientais/metabolismo , Pulmão/metabolismo , Metais/metabolismo , Animais , Pequim
7.
Sensors (Basel) ; 18(11)2018 Nov 09.
Artigo em Inglês | MEDLINE | ID: mdl-30423992

RESUMO

In arid and semi-arid regions, identifying and monitoring of soil alkalinity and salinity are in urgently need for preventing land degradation and maintaining ecological balances. In this study, physicochemical, statistical, and spectral analysis revealed that potential of hydrogen (pH) and electrical conductivity (EC) characterized the saline-alkali soils and were sensitive to the visible and near infrared (VIS-NIR) wavelengths. On the basis of soil pH, EC, and spectral data, the partial least squares regression (PLSR) models for estimating soil alkalinity and salinity were constructed. The R² values for soil pH and EC models were 0.77 and 0.48, and the root mean square errors (RMSEs) were 0.95 and 17.92 dS/m, respectively. The ratios of performance to inter-quartile distance (RPIQ) for the soil pH and EC models were 3.84 and 0.14, respectively, indicating that the soil pH model performed well but the soil EC model was not considerably reliable. With the validation dataset, the RMSEs of the two models were 1.06 and 18.92 dS/m. With the PLSR models applied to hyperspectral data acquired from the hyperspectral imager (HSI) onboard the HJ-1A satellite (launched in 2008 by China), the soil alkalinity and salinity distributions were mapped in the study area, and were validated with RMSEs of 1.09 and 17.30 dS/m, respectively. These findings revealed that the hyperspectral images in the VIS-NIR wavelengths had the potential to map soil alkalinity and salinity in the Songnen Plain, China.

8.
Ecotoxicology ; 25(3): 439-46, 2016 Apr.
Artigo em Inglês | MEDLINE | ID: mdl-26703383

RESUMO

Biomonitoring provides direct evidence of the bioavailability and accumulation of toxic elements in the environment and in the current study, homing pigeons were used as a biomonitor of atmospheric pollution in Beijing and Guangzhou, China. Cadmium (Cd), lead (Pb), and mercury (Hg) concentrations were measured in lung, kidney, and liver tissues of 25 homing pigeons collected from Beijing (n = 15) and Guangzhou (n = 10). Cadmium concentrations in all tissue and lung Pb concentrations were significantly greater in pigeons collected from Guangzhou compared to those collected from Beijing. Lung Cd and Pb concentrations corresponded to differences in ambient air concentrations between the two cities, suggesting that homing pigeons are valuable biomonitors of atmospheric metal contamination. Liver and kidney Hg concentrations were significantly greater in pigeons collected from Beijing compared to those collected from Guangzhou, while Hg concentrations in lung tissue were not significantly different. Results of the current study support a conclusion that homing pigeons provide valuable data for evaluating exposure and potential effects to environmental metal concentrations.


Assuntos
Poluentes Atmosféricos/metabolismo , Columbidae/metabolismo , Monitoramento Ambiental , Metais/metabolismo , Animais , Pequim , Cidades
9.
J Environ Sci (China) ; 31: 194-202, 2015 May 01.
Artigo em Inglês | MEDLINE | ID: mdl-25968273

RESUMO

Using a liquid-solid phase inversion method, a hybrid matrix poly(vinylidene fluoride) (PVDF) membrane was prepared with alumina (Al2O3) nanoparticle addition. Pd/Fe nanoparticles (NPs) were successfully immobilized on the Al2O3/PVDF membrane, which was characterized by Scanning Electron Microscopy (SEM) and Transmission Electron Microscopy (TEM). The micrographs showed that the Pd/Fe NPs were dispersed homogeneously. Several important experimental parameters were optimized, including the mechanical properties, contact angle and surface area of Al2O3/PVDF composite membranes with different Al2O3 contents. At the same time, the ferrous ion concentration and the effect of hydrophilization were studied. The results showed that the modified Al2O3/PVDF membrane functioned well as a support. The Al2O3/PVDF membrane with immobilized Pd/Fe NPs exhibited high efficiency in terms of dichloroacetic acid (DCAA) dechlorination. Additionally, a reaction pathway for DCAA dechlorination by Pd/Fe NPs immobilized on the Al2O3/PVDF membrane system was proposed.


Assuntos
Óxido de Alumínio/química , Ferro/química , Nanopartículas Metálicas/química , Paládio/química , Polivinil/química , Ácido Dicloroacético/química , Membranas Artificiais , Microscopia Eletrônica de Varredura , Microscopia Eletrônica de Transmissão , Estrutura Molecular
10.
Ecotoxicology ; 23(4): 609-17, 2014 May.
Artigo em Inglês | MEDLINE | ID: mdl-24420619

RESUMO

It is necessary to estimate heavy metal concentrations and risk in surface water for understanding the heavy metal contaminations and for sustainable protection of ecosystems and human health. To investigate the anthropogenic contribution of heavy metal accumulation surrounding an industrial city in China, the concentrations of six heavy metals, including mercury (Hg), arsenic (As), chromium (Cr), lead (Pb), copper (Cu), and cadmium (Cd) were examined; from four different regions of Daqing in autumn 2011 and winter 2012. The results showed heavy metals distributed in the industrial area at concentrations relatively higher than those in other three areas, while concentrations in the farming area and the protected area were lower. The heavy metal concentrations of water bodies in all areas, except those for Hg and As, Cu, Pb and Cr were lower than the cutoff values for the Class I water quality that was set as the highest standard to protect the national nature reserves. While Hg and As of lakes in industry region had a higher level than those in the agriculture and landscape water, the lowest allowed. The concentrations of all the heavy metals in winter were higher than in the autumn. Cu had a higher ecological risks level to freshwater organisms. The discharge of urban sewage and industrial wastewater might be a major pollutant source, thus these sources should identified before remediation efforts. Efforts are needed to protect the lakes from pollution and also to reduce environmental health risks. This study and the valuable data will pave the way for future research on these Lakes in Daqing.


Assuntos
Monitoramento Ambiental , Metaloides/análise , Metais Pesados/análise , Poluentes Químicos da Água/análise , China , Humanos , Lagos , Metaloides/toxicidade , Metais Pesados/toxicidade , Medição de Risco , Estações do Ano , Poluentes Químicos da Água/toxicidade
11.
Ecotoxicology ; 23(4): 601-8, 2014 May.
Artigo em Inglês | MEDLINE | ID: mdl-24420623

RESUMO

There is growing concern for the lake environment because polluted sediments may cause ecotoxicological effects. In the current study, persistent organochlorine compounds (OCPs), including hexachlorocyclohexanes (HCHs), dichlorodiphenyltrichloroethanes (DDTs) and cyclodienes, were analyzed in core sediments taken from Huoshaohei Lake, Xihulu Lake, Wanghua Lake and Keqin Lake, Heilongjiang Province, China. The total OCPs concentrations ranged from 0.92 to 7.09, 0.15 to 9.95, 0.19 to 1.84 and 0.06 to 3.52 ng/g, respectively. The most dominant pollutants were the HCHs, high proportions of γ-HCH isomer indicating the recent input of lindane. The ratios of α-HCH/γ-HCH of four lakes are all lower than that in technical HCH mixtures indicating that there was input of lindane in the past several years, and the mean ratios of (DDE+DDD)/DDTs are all <0.5, suggesting recent release of DDT compounds. Compared with the corresponding ecological environmental quality guidelines from Ingersoll and base on the model of risk based corrective action environmental health risk assessment, the sediments from the four lakes poses a lower potential hazard to human health and the environment but still should be taken into account.


Assuntos
Monitoramento Ambiental , Poluentes Ambientais/análise , Hidrocarbonetos Clorados/análise , Praguicidas/análise , China , Sedimentos Geológicos/análise , Lagos , Medição de Risco
12.
Ecotoxicology ; 23(4): 518-26, 2014 May.
Artigo em Inglês | MEDLINE | ID: mdl-24414855

RESUMO

Concentrations of the Cu, Cd, Cr, As, Zn and Ni in water samples from 272 sampling stations in the water environment of Zhalong Wetland, China were studied. Health risk assessment associated with six heavy metals and metalloid was conducted using health risk assessment model from United States Environmental Protection Agency. It can be concluded that the mean concentrations of Cu, Ni, Zn, As, Cd and Cu were 0.19, 0.45, 0.52, 4.9, 0.12 and 0.24 µg L(-1), respectively. The carcinogenic risk of Cr, As and Cd in the discharged area, experimental area, buffer area and core area were lower than the maximum allowance risk level recommended by International Commission on Radiological Protection (ICRP 5.0 × 10(-5) a(-1)). The non-carcinogenic risks (Cu, Zn, Ni) was also lower than the maximum allowance levels recommended by ICRP. Though it was lower than the level, it was very approaching to maximum acceptable risk level, need to draw attention to the relevant departments.


Assuntos
Monitoramento Ambiental , Metaloides/análise , Metais Pesados/análise , Poluentes Químicos da Água/análise , China , Humanos , Neoplasias/induzido quimicamente , Análise de Componente Principal , Medição de Risco , Áreas Alagadas
13.
Ecotoxicology ; 23(4): 480-5, 2014 May.
Artigo em Inglês | MEDLINE | ID: mdl-24468926

RESUMO

Phosphorus content and its species were studied for the core sediments of Delong Lake, using the SMT sequential extraction method, and then were correlated to the contents of total nitrogen and organic matter. According to (210)Pb and (137)Cs dating, the historical profiles of 33 cm core sediments were generated. The objective of this study was to understand how nutrients of lake sediments evolved in order to get insights into the effect of human activities on their sedimentary history. The nutrients contents in the core sediments slowly increased after 1957, showing the human activity influence the natural deposition of the lake sediment. From 1978 to 1985, various nutrients in the lake sediment rapid increased, showing that the human activities strengthened. From 2003 to now, most of nutrients in the sediment rapidly increased and significantly modified the natural deposition of the lake sediment.


Assuntos
Poluição Ambiental/análise , Sedimentos Geológicos/análise , Fósforo/análise , China , Lagos/análise , Nitrogênio/análise , Compostos Orgânicos/análise
14.
Ecotoxicology ; 23(4): 589-600, 2014 May.
Artigo em Inglês | MEDLINE | ID: mdl-24420622

RESUMO

The spatial distribution, sources, and potential ecological risk of heavy metals and metalloid were evaluated in sediments of the Wuyuer River and its tributaries. Metal and metalloid concentrations and chemical speciation (Cr, Cu, Ni, Pb, Cd, As, Zn and Hg) in 187 surface sediment samples were measured using inductively coupled plasma mass spectrometry. Metals and metalloid in the sediments of the Wuyuer River were greater than the background values of the Songnen Plain, and mean heavy metal concentrations were greater in downstream segments of the river than in upstream segments. Speciation results indicated that Cd was chemically mobile and Cu, Pb, Zn, Cr, and Ni were potentially bioavailable. Mercury and As existed mainly in the residual fraction. Hakanson's potential risk index indicated that the total potential ecological risk of these elements was moderate in the Wuyuer River. Among the selected metals and metalloid, Hg and Cd were the most potentially toxic and mainly distributed near the cities of Keshan, Yi'an and Fuyü. Because the speciation of Cd in the river sediments is highly bioavailable, the concentrations of Cd should be closely monitored. This research provides managers with information needed to better regulate the environment of the Wuyuer River.


Assuntos
Monitoramento Ambiental , Sedimentos Geológicos/análise , Metaloides/análise , Metais Pesados/análise , China , Análise Multivariada , Medição de Risco , Rios
15.
Ecotoxicology ; 23(4): 681-8, 2014 May.
Artigo em Inglês | MEDLINE | ID: mdl-24407844

RESUMO

Sediment core samples from Nashina Lake, Heilongjiang, China were collected using a gravity sampler. The cores were sliced horizontally at 1 cm each to determine the particle size, total concentrations and speciation of Cd, Cr, Cu, Mn, Ni, Pb, and Zn. Total concentrations of heavy metals were extracted using an acid mixture (containing hydro fluoric acid, nitric acid, and sulphuric acid) and analyzed using an inductively coupled plasma spectrometry. A sequential extraction procedure was employed to separate chemical species. Analysis of results indicate that the concentrations of heavy metals in the sediments of Nashina Lake in descending order are Mn, Cr, Zn, Pb, Ni, Cu, and Cd. The ratios of the average concentrations of four heavy metals (e.g.Cr, Cu, Ni, Zn) to their background values were >1; and those of Mn, Cd, and Pb were >1. Moreover, some toxic metals were mainly distributed in bioavailable fractions. For instance, both Cd and Mn were typically found in Acid-extractable species or Fe-Mn oxide species, and thus can be easily remobilized and enter the food chain. Finally, the analysis of geo-accumulation index showed that anthropogenic pollution levels of Cr, Cu, Mn, Ni, Zn were low, but those of Pb and Cd were at the moderate level. As both Pb and Cd are toxic metals, it is highly necessary to prohibit their transformation and accumulation in the sediments.


Assuntos
Monitoramento Ambiental , Sedimentos Geológicos/análise , Metais Pesados/análise , Poluição da Água , China , Sedimentos Geológicos/química , Lagos , Metais Pesados/química
16.
Ecotoxicology ; 23(4): 527-37, 2014 May.
Artigo em Inglês | MEDLINE | ID: mdl-24609408

RESUMO

Lianhuan Lake is found in the lowest point of the Songnen Plain in Eastern China and is a typical hardwater lake. Lianhuan Lake is constituted by eighteen lakes and Aobaopao Lake is located in the eastern portion. Geochemical features and pollution history of heavy metals in Aobaopao Lake were investigated. Total metal contents and chemical fractionations of Cu, Fe, Mn, Ni, Pb, Cd, Cr and Zn were analyzed for core sediment samples taken from north sampling site for Core AB1 and south sampling site for Core AB2 of the lake using the speciation extraction procedure proposed by the Commission of the European Communities Bureau of Reference (BCR) together with grain size and TOC measurements. Heavy metal analyses showed that sediments have similar geochemical features. In order to quantify the anthropogenic contamination of the metals according to their speciation composition, the RSP approach was applied. In Core AB1, Cd is moderate and significant contaminate while Mn is minor, moderate and significant contamination. In Core AB2, Cd is more significant contaminate from 3.75 cm to the surface. The risk assessment code (RAC) established by Perin et al. (Heavy Metals in the Environment, CEP Consultants, Edinburgh, 1985) was used to evaluate the risk of heavy metals in sediments of Aobaopao Lake. The results for both cores suggest that Mn and Cd posed a high risk to local environment.


Assuntos
Monitoramento Ambiental , Sedimentos Geológicos/análise , Metais Pesados/análise , China , Lagos , Medição de Risco
17.
Ecotoxicology ; 22(10): 1490-7, 2013 Dec.
Artigo em Inglês | MEDLINE | ID: mdl-24100781

RESUMO

Biomonitoring provides direct evidence of the bioavailability and accumulation of toxic elements in the environment. In the current study, 1-2, 5-6, and 9-10+ year old homing pigeons collected from the Haidian District of Beijing during 2011 were necropsied and concentrations of cadmium, lead, and mercury were measured in liver, lung, and kidney tissue. At necropsy, gray/black discoloration of the margins of the lungs was observed in 98 % of the pigeons. There were no significant differences in metal concentrations as a function of gender. Cadmium concentrations in all tissues and Pb concentrations in the lung tissues were significantly greater in 9-10+ year old pigeons compared to other age groups indicating that Cd and Pb were bioavailable. Mercury concentrations were not significantly different among age groups. Cadmium concentrations in kidney and lung tissues of 9-10+ year old pigeons were similar to or exceeded concentrations of Cd reported in pigeons from another high traffic urban area and most wild avian species from Korea suggesting that Cd in this region of Beijing may be of concern. Homing pigeons provide valuable exposure and bioaccumulation data not readily available from air monitoring alone, thus providing information regarding potential health effects in wildlife and humans in urban areas. As environmental quality standards are implemented in China, homing pigeons will serve as a valuable bio-monitor of the efficacy of these actions.


Assuntos
Cádmio/toxicidade , Columbidae/metabolismo , Exposição Ambiental , Monitoramento Ambiental/métodos , Poluentes Ambientais/toxicidade , Chumbo/toxicidade , Mercúrio/toxicidade , Fatores Etários , Animais , China , Cidades , Feminino , Rim/metabolismo , Fígado/metabolismo , Pulmão/metabolismo , Masculino , Fatores Sexuais
18.
Environ Sci Pollut Res Int ; 30(54): 115556-115570, 2023 Nov.
Artigo em Inglês | MEDLINE | ID: mdl-37884719

RESUMO

The high value resource utilization of corn straw is a long-term problem at present and in the future. Biochar preparation is an important utilization way of corn straw. The research on city tail water treated by constructed wetland (CW) with biochar was carried out to further increase the wastewater treatment capacity of the CW. Surface characterization, structural characteristics, and adsorption of straw biochar modified by different acids were measured. The study found that the ability of H2SO4 to remove ash from biochar was stronger than other acids and H2SO4-biochar was easy to be cleaned without H2SO4 residue. The performance of biochar modified by H2SO4 was obviously better than other acids, and the biochar adsorption was enhanced. The modification of biochar substrate modified by H2SO4 in CW reduced the change of electrical conductivity (EC) and promoted denitrification. H2SO4-modified biochar promoted the absorption of N and P by Iris pseudacorus L. The compound modification effect of straw biochar was obvious. The results revealed the acid modification characteristics of straw biochar, which were beneficial for increasing the wastewater treatment rate by CW. This study will promote the sustainable development of CW.


Assuntos
Áreas Alagadas , Zea mays , Carvão Vegetal/química , Adsorção
19.
Environ Sci Pollut Res Int ; 30(50): 108582-108595, 2023 Oct.
Artigo em Inglês | MEDLINE | ID: mdl-37752393

RESUMO

Constructed wetland (CW) is an important method of ecological water treatment, and CW has obvious advantage in treating low-pollution water. In order to improve the treatment efficiency of CW, the first-order and second-order kinetics simulations of pollutant removal in CW were carried out to optimize operating conditions. The experimental study of city tail water treatment under unmodified biochar (different additions) or different modified biochar conditions showed that the first-order kinetic equation relatively accurately reflect the removal of pollutants by substrate. The relatively optimal range of biochar addition (2.21-3.79%) in the first-order kinetic analysis covered the relatively optimal mass ratio (2.95%). The first-order kinetic equation fitting showed that the half-life of ammonia nitrogen removal by NaOH (0.1 mol·L-1)-modified biochar was reduced by about 10% without plant. The half-life of total phosphorus removal by KMnO4 (0.1 mol·L-1) modified biochar was reduced by about 50%. The half-life of chemical oxygen demand removal by H2SO4 (0.75 mol·L-1) + 8 freeze-thaw cycles modified biochar was reduced by about 9.0%. When the half-life was small, the pollutant removal rate was high. The results of this study further confirmed the effectiveness of the simulation results of pollutant removal in CW with biochar by the first-order kinetic equation. This study further optimized the CW operating conditions and improved the treatment efficiency of nitrogen and phosphorus in the CW.


Assuntos
Poluentes Ambientais , Purificação da Água , Áreas Alagadas , Cinética , Purificação da Água/métodos , Nitrogênio , Fósforo , Eliminação de Resíduos Líquidos/métodos
20.
Chemosphere ; 331: 138785, 2023 Aug.
Artigo em Inglês | MEDLINE | ID: mdl-37121285

RESUMO

Spatiotemporal variation of PM2.5 in 2018 and 2020 were compared to analyze the impacts of COVID-19, the spatial heterogeneity of PM2.5, and meteorological and socioeconomic impacts of PM2.5 concentrations heterogeneity in China in 2020 were investigated. The results showed that the annual average PM2.5 concentration in 2020 was 32.73 µg/m3 existing a U-shaped variation pattern, which has decreased by 6.38 µg/m3 compared to 2018. A consistent temporal pattern was found in 2018 and 2020 with significant high values in winter and low in summer. PM2.5 declined dramatically in eastern and central China, where are densely populated and economically developed areas during the COVID-19 epidemic compared with previous years, indicating that the significantly decline of social activities had an important effect on the reduction of PM2.5 concentrations. The lowest PM2.5 was found in August because that precipitation had a certain dilution effect on pollutants. January was the most polluted due to centralized coal burning for heating in North China. Overall, the PM2.5 concentrations in China were spatially agglomerated. The highly polluted contiguous zones were mainly located in northwest China and the central plains city group, while the coastal area and Inner Mongolia were areas with good air quality. Negative correlations were found between natural factors (temperature, precipitation, wind speed and relative humidity) and PM2.5 concentrations, with precipitation has the greatest impact on PM2.5, which are beneficial for reducing PM2.5 concentrations. Among the socio-economic factors, proportion of the secondary industry, number of taxis, per capita GDP, population, and industrial nitrogen oxide emissions have positive correlation effects on PM2.5, while the overall social electricity consumption, industrial sulfur dioxide emissions, green coverage in built-up areas, and total gas and liquefied gas supply have negative correlation effects on the PM2.5.


Assuntos
Poluentes Atmosféricos , Poluição do Ar , COVID-19 , Humanos , Poluentes Atmosféricos/análise , Material Particulado/análise , COVID-19/epidemiologia , Poluição do Ar/análise , China/epidemiologia , Estações do Ano , Fatores Socioeconômicos , Monitoramento Ambiental/métodos , Cidades
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