Programmable Microfluidics Enabled by 3D Printed Bionic Janus Porous Matrics for Microfluidic Logic Chips.

Numerous structures have been functionally optimized for directional liquid transport in nature. Inspired by lush trees' xylem that enable liquid directional transportation from rhizomes to the tip of trees, a new kind of programmable microfluidic porous matrices using projection micro-stereolithography (PµSL) based 3D printing technique is fabricated. Structural matrices with internal superhydrophilicity and external hydrophobicity are assembled for ultra-fast liquid rising enabled by capillary force. Moreover, the unidirectional microfluidic performance of the bionic porous matrices can be theoretically optimized by adjusting its geometric parameters. Most significantly, the successive programmable flow of liquid in a preferred direction inside the bionic porous matrices with tailored wettability is achieved, validating by a precisely printed liquid displayer and a microfluidic logic chip. The programmable and functional microfluidic matrices promise applications of patterned liquid flow, displayer, logic chip, cell screening, gas-liquid separation, and so on.

Untethered microgripper-the dexterous hand at microscale.

Untethered microgrippers that can navigate in hard-to-reach and unpredictable environments are significantly important for biomedical applications such as targeted drug delivery, micromanipulation, minimally invasive surgery and in vivo biopsy. Compared with the traditional tethered microgrippers, the wireless microgrippers, due to the exceptional characteristics such as miniaturized size, untethered actuation, dexterous and autonomous motion, are projected to be promising microtools in various future applications. In this review, we categorize the untethered microgrippers into five major classes, i.e. microgrippers responsive to thermal, microgrippers actuated by magnetic fields, microgrippers responsive to chemicals, light-driven microgrippers and hybrid actuated microgrippers. Firstly, the actuation mechanisms of these microgrippers are introduced. The challenges faced by these microgrippers are also covered in this part. With that, the fabrication methods of these microgrippers are summarized. Subsequently, the applications of microgrippers are presented. Additionally, we conduct a comparison among different actuation mechanisms to explore the advantages and potential challenges of various types of microgrippers. In the end of this review, conclusions and outlook of the development and potential applications of the microgrippers are discussed.

Boron-doped three-dimensional porous carbon framework/carbon shell encapsulated silicon composites for high-performance lithium-ion battery anodes.

Deleterious volumetric expansion and poor electrical conductivity seriously hinder the application of Si-based anode materials in lithium-ion batteries (LIBs). Herein, boron-doped three-dimensional (3D) porous carbon framework/carbon shell encapsulated silicon (B-3DCF/Si@C) hybrid composites are successfully prepared by two coating and thermal treatment processes. The presence of 3D porous carbon skeleton and carbon shell effectively improves the mechanical properties of the B-3DCF/Si@C electrode during the cycling process, ensures the stability of the electrical contacts of the silicon particles and stabilizes the solid electrolyte interface (SEI) layer, thus enhancing the electronic conductivity and ion migration efficiency of the anode. The developed B-3DCF/Si@C anode has a high reversible capacity, excellent cycling stability and outstanding rate performance. A reversible capacity of 1288.5 mAh/g is maintained after 600 cycles at a current density of 400 mA g-1. The improved electrochemical performance is demonstrated in a full cell using a LiFePO4-based cathode. This study presents a novel approach that not only mitigates the large volume expansion effects in LIB anode materials, but also provides a reference model for the preparation of porous composites with various functionalities.

Super Water-Storage Self-Adhesive Gel for Solar Vapor Generation and Collection.

Water treatment consumes lots of energy from fossil fuels nowadays, and the emission of CO2 enhances the temperature on earth, resulting in more and more hazards. Thus, clean water production enabled by green energy without CO2 emission is attracting more and more attention. Herein, we propose a novel solar evaporation system achieving both solar evaporation and water storage with two different unique hydrogels based on a three-dimensional (3D) printing technique. The hydrogel absorber demonstrates an ultrahigh absorptance (98.2%) of solar light, while the water-storage hydrogel absorbs more than 100 times its own weight of water, demonstrating super water-storage performance with strong self-adhesiveness. The solar vapor generation rate can be as high as 3.14 kg·m-2·h-1, with a solar evaporation efficiency up to 91.2% irradiated by 1.43 sun. Furthermore, our environmentally friendly solar evaporation system achieves ultrahigh water purification efficiency of 99.99% for salt, heavy ions, and acid/alkaline with remarkable stability and durability. Our solar evaporation system promises long-lasting applications for the hydrological cycle enabled by solar energy, such as seawater desalination, sterilization, wastewater purification, and so on.

3D-Printed Complex Microstructures with a Self-Sacrificial Structure Enabled by Grayscale Polymerization and Ultrasonic Treatment.

Complex three-dimensional (3D) microstructures are attracting more and more attention in many applications such as microelectromechanical systems, biomedical engineering, new materials, new energy, environmental protection, and wearable electronics. However, fabricating complex 3D microstructures by 3D printing techniques, especially those with long suspended structures, needs to introduce additional supporting structures, which are difficult to be removed. Here, we propose a simple method in which the supporting structures can be easily removed by optimizing their size and the grayscale value working with ultrasonic treatment in ethanol solution. The 3D microstructures and the supporting structures made of the same insoluble materials are fabricated simultaneously by using a projection microstereolithography system with a dynamic mask. The results demonstrate that the supporting structures play a key role in the fabrication of the long suspended structures while they can be easily removed. The removal time decreases with the increase in the height of the supporting microstructures, and the breaking force and shearing force of the supporting structures increase with the increase in their grayscale and the diameter. In addition, theory and the multiphysics simulation validate that the stress concentration at the top and the bottom of the supporting structures due to the cavitation from ultrasonic vibration dominates the removal of the supporting structures. Finally, a tree-like structure is precisely fabricated by using our method. The present study provides a new way for the removal of the supporting structures for 3D printed suspended microstructures.

Rise of cyborg microrobot: different story for different configuration.

By integrating organic parts achieved through evolution and inorganic parts developed by human civilisation, the cyborg microrobot is rising by taking advantage of the high flexibility, outstanding energy efficiency, extremely exquisite structure in the natural components and the fine upgradability, nice controllability in the artefact parts. Compared to the purely synthetic microrobots, the cyborg microrobots, due to the exceptional biocompatibility and biodegradability, have already been utilised in in situ diagnosis, precise therapy and other biomedical applications. In this review, through a thorough summary of recent advances of cyborg microrobots, the authors categorise the cyborg microrobots into four major classes according to the configuration between biomaterials and artefact materials, i.e. microrobots integrated inside living cell, microrobots modified with biological debris, microrobots integrated with single cell and microrobots incorporated with multiple cells. Cyborg microrobots with the four types of configurations are introduced and summarised with the combination approaches, actuation mechanisms, applications and challenges one by one. Moreover, they conduct a comparison among the four different cyborg microrobots to guide the actuation force promotion, locomotion control refinement and future applications. Finally, conclusions and future outlook of the development and potential applications of the cyborg microrobots are discussed.