Versatile Metal-Organic Framework Incorporating Ag2S for Constructing a Photoelectrochemical Immunosensor for Two Breast Cancer Markers.

Breast cancer poses the significance of early diagnosis and treatment. Here, we developed an innovative photoelectrochemical (PEC) immunosensor characterized by high-level dual photocurrent signals and exceptional sensitivity. The PEC sensor, denoted as MIL&Ag2S, was constructed by incorporating Ag2S into a metal-organic framework of MIL-101(Cr). This composite not only enhanced electron-hole separation and conductivity but also yielded robust and stable dual photocurrent signals. Through the implementation of signal switching, we achieved the combined detection of cancer antigen 15-3 (CA15-3) and carcinoembryonic antigen (CEA) with outstanding stability, reproducibility, and specificity. The results revealed a linear range for CEA detection spanning 0.01-32 ng/mL, with a remarkably low detection limit of 0.0023 ng/mL. Similarly, for CA15-3 detection, the linear range extended from 0.1 to 320 U/mL, with a low detection limit of 0.014 U/mL. The proposed strategy introduces new avenues for the development of highly efficient, cost-effective, and user-friendly PEC sensors. Furthermore, it holds promising prospects for early clinical diagnosis, contributing to potential breakthroughs in medical detection and ultimately improving patient outcomes.

Atomic layer deposition of ZnO on polypropylene nonwovens for photocatalytic antibacterial facemasks.

Addressing respiratory infectious diseases remains one of the main priorities due to the increased risk of exposure caused by population growth, increasing international travel and commerce, and most recently, the COVID-19 outbreak. In the war against respiratory diseases, facemasks are powerful tools to obstruct the penetration of microorganisms, thereby protecting the wearer from infections. Nonetheless, the intercepted microorganisms on the surface of facemasks may proliferate and lead to secondary infection. To solve this problem, atomic layer deposition is introduced to deposit uniform and mechanically robust ZnO layers on polypropylene (PP) nonwoven fabrics, a widely used raw material in fabricating facemasks. The loading of ZnO demonstrates no adverse effects on the separation performance of facemasks, and the filtration efficiency of the facemasks towards different types of nanoparticles remains higher than 98.9%. Moreover, the modified PP nonwoven fabrics are granted with excellent antibacterial activity and photocatalytic sterilization ability, which can inactivate both germ-negative and germ-positive bacteria (E. coliandS. aureus) effectively with and without light illumination. Therefore, the modified PP nonwoven fabrics are potential candidates to be used as the outer layer on facemasks and endow them with photocatalytic antibacterial activity.

Biocompatible curcumin coupled nanofibrous membrane for pathogens sterilization and isolation.

Airborne transmission of pathogens is the most probable cause for the spread of respiratory diseases, which can be intercepted by personal protective equipment such as masks. In this study, an efficient antiviral personal protective filter was fabricated by coupling the biocompatible curcumin (CCM) with nanofibrous polytetrafluoroethylene (PTFE) membrane. The CCM extracted from plants was first dissolved in acidified ethanol at a certain pH and temperature to optimize its loading concentration, antiviral activation, and binding forces on the polyethylene terephthalate (PET) support to form a pre-filtration layer at the front section of the filter. Ultrathin PTFE membrane was then fabricated on the antibacterial-antiviral PET support (A-A PET) by controllable heating lamination. This functional layer of the filter exhibits good gas permeance (3423.6 m3/(m2·h·kPa)) and ultrafine particles rejection rate (>98.79%). Moreover, the obtained A-A filter exhibit a high antibacterial rate against a variety of bacteria (E. coli, B. subtilis, A. niger, and Penicillium were 99.84%, 99.02%, 93.60%, 95.23%, respectively). Forthwith virucidal (SARS-CoV-2) efficiency of the A-A filter can reach 99.90% for 5 min. The filter shows good stability after 10 heating cycles, demonstrating its reusability.

Meltblown fabric vs nanofiber membrane, which is better for fabricating personal protective equipments.

The coronavirus disease 2019 (COVID-19) pandemic has led to a great demand on the personal protection products such as reusable masks. As a key raw material for masks, meltblown fabrics play an important role in rejection of aerosols. However, the electrostatic dominated aerosol rejection mechanism of meltblown fabrics prevents the mask from maintaining the desired protective effect after the static charge degradation. Herein, novel reusable masks with high aerosols rejection efficiency were fabricated by the introduction of spider-web bionic nanofiber membrane (nano cobweb-biomimetic membrane). The reuse stability of meltblown and nanofiber membrane mask was separately evaluated by infiltrating water, 75% alcohol solution, and exposing under ultraviolet (UV) light. After the water immersion test, the filtration efficiency of meltblown mask was decreased to about 79%, while the nanofiber membrane was maintained at 99%. The same phenomenon could be observed after the 75% alcohol treatment, a high filtration efficiency of 99% was maintained in nanofiber membrane, but obvious negative effect was observed in meltblown mask, which decreased to about 50%. In addition, after long-term expose under UV light, no filtration efficiency decrease was observed in nanofiber membrane, which provide a suitable way to disinfect the potential carried virus. This work successfully achieved the daily disinfection and reuse of masks, which effectively alleviate the shortage of masks during this special period.

In Situ-Grown Al2O3 Nanoflowers and Hydrophobic Modification Enable Superhydrophobic SiC Ceramic Membranes for Membrane Distillation.

Membrane distillation (MD) is considered a promising technology for desalination. In the MD process, membrane pores are easily contaminated and wetted, which will degrade the permeate flux and salt rejection of the membrane. In this work, SiC ceramic membranes were used as the supports, and an Al2O3 micro-nano structure was constructed on its surface. The surface energy of Al2O3@SiC micro-nano composite membranes was reduced by organosilane grafting modification. The effective deposition of Al2O3 nanoflowers on the membrane surface increased membrane roughness and enhanced the anti-fouling and anti-wetting properties of the membranes. Simultaneously, the presence of nanoflowers also regulated the pore structures and thus decreased the membrane pore size. In addition, the effects of Al2(SO4)3 concentration and sintering temperature on the surface morphology and performance of the membranes were investigated in detail. It was demonstrated that the water contact angle of the resulting membrane was 152.4°, which was higher than that of the pristine membrane (138.8°). In the treatment of saline water containing 35 g/L of NaCl, the permeate flux was about 11.1 kg⋅m-2⋅h-1 and the salt rejection was above 99.9%. Note that the pristine ceramic membrane cannot be employed for MD due to its larger membrane pore size. This work provides a new method for preparing superhydrophobic ceramic membranes for MD.

Novel Membranes for Environmental Application.

Membrane-based separations for water purification and gas separation have been applied extensively to address the global challenges of water scarcity and the pollution of aquatic and air environments [...].

Spatially confined growth of carbon nanotubes in the pore channels of microporous ceramic supports with improved filtration efficiency.

Carbon nanotubes (CNTs) with high degrees of uniformity, orientation and controlled dimensions on porous supports are highly desirable for various applications such as separation of O/W emulsions and air purification. In this work, CNTs were fabricated on silicon carbide (SiC) porous supports with different porosities and pore sizes by chemical vapor deposition (CVD). The growth processes of CNTs on the surface and in the pore channels of the SiC support were studied in detail. Based on microstructural characterization by SEM, Raman spectroscopy and TEM, it was found that these CNTs grown in the pore channels of SiC supports had a higher degree of orientation and purity than those grown on the surface due to the spatially confined effect. The growth processes of various types of CNTs on the microporous supports were proposed, which were further verified by CNTs with different steric configurations (S-CNTs and VACNTs) and on Al2O3 porous supports. Moreover, the contribution of CNTs in the pore channels to the filtration efficiency was demonstrated in oil-water emulsion separation and particle removal in air. This work provides significant guidance for the preparation and filtration application of CNTs on porous materials.

A new comprehensive evaluation indicator of adsorbent for gas separation.

To evaluate and compare the performances of different adsorbents for gas separation, an adsorbent comprehensive evaluation indicator (ACEI) is proposed. In the ACEI, the working capacity, selectivity, adsorption rate, regeneration and circulation parameters, stability during adsorption, and tolerance to impurities are considered, and some exponents are introduced to allow the ACEI to adapt to different adsorbent working conditions. To illustrate the applicability of the ACEI, the adsorption of CO2 and N2 was investigated on two kinds of activated carbons (ACs), which were used for gas purification and bulk separation. The ACEI is a better overall indicator than other currently used indicators to evaluate the performance of adsorbents.

Silicon carbide microfiltration membranes for oil-water separation: Pore structure-dependent wettability matters.

Both the pore size and surface properties of silicon carbide (SiC) membranes are demonstrated to significantly affect their separation efficiency when used for oily water treatment. However, the potential influences of open porosity together with the pore size of SiC membranes on their surface properties and oil-water separation performance have rarely been investigated. In this work, porous SiC ceramic membranes with tunable open porosity and pore size were purposely prepared and selected to systematically study the effect of pore structure-dependent wettability on the oil-water separation performance. The measured pure water flux of selected membranes as a function of open porosity (34-48%) and pore size (0.43-0.67 µm) was well-fitted by using a modified H-P equation. Interestingly, the hydrophilicity of SiC membranes was improved with the increase in open porosity and pore size, as evidenced by the gradually decreased dynamic water contact angle and underwater adhesion of oil droplets. Further, the open porosity of SiC membranes was found to contribute more to the improved surface wettability. As a result, the stable flux of SiC membranes in oil-in-water (O/W) emulsions was increased by 24% with the increased open porosity while the oil rejection rate remained above 90%. This work quantitatively reveals the contributions of the pore structure to the surface wettability of ceramic membranes, and thus provides an effective pathway to improve their performance in oil-water separation.

Nanoarchitectonics for Electrospun Membranes with Asymmetric Wettability.

Membranes with asymmetric wettability have attracted significant interest by virtue of their unique transport characteristics and functionalities arising from different wetting behaviors of each membrane surface. The cross-sectional wettability distinction enables a membrane to realize directional liquid transport or multifunction integration, resulting in rapid advance in applications, such as moisture management, fog collection, oil-water separation, and membrane distillation. Compared with traditional homogeneous membranes, these membranes possess enhanced transport performance and higher separation efficiency owing to the synergistic or individual effects of asymmetric wettability. This Review covers the recent progress in fabrication, transport mechanisms, and applications of electrospun membranes with asymmetric wettability and provides a perspective on future development in this important area.

Treatment of vegetable oily wastewater using an integrated microfiltration-reverse osmosis system.

Vegetable oil processing plants and catering trade often generate a large amount of oil-containing wastewater, which causes serious environmental problems. The objective of this work was to explore the feasibility of vegetable oil wastewater treatment with an integrated microfiltration-reverse osmosis (MF-RO) process. The influence of operational parameters on the separation behaviors were investigated in MF process. In MF continuous process the steady flux was around 90 (L/m(2) h) when the concentrated multiple reached 16, and the oil content in permeate was less than 12 mg/L. In the RO continuous process, antifouling membrane was used to treat permeate from the ceramic membrane process in order to improve the water quality. The RO process had a permeate flux of 24 (L/m(2) h) and water recovery rate of 95%. The permeate from the RO stage was free of oil, and its TOC and conductivity were less than 0.6 mg/L and 50 micros/cm, respectively. The results demonstrated that the two stage membrane process combining MF and RO is highly efficient in the treatment of oil-containing wastewater.

Multifunctional hybrid porous filters with hierarchical structures for simultaneous removal of indoor VOCs, dusts and microorganisms.

Air purification often requires multiple layers of filters with different functions to remove various air pollutants, which lead to high pressure drop, high air flow path and frequent filter replacement. In this work, a novel multifunctional Ag@MWCNTs/Al2O3 hybrid filter with a depth-type hierarchical structure for simultaneous removal of fine particles, microorganisms and VOCs was designed and fabricated. The novel hybrid air filter showed leading air purification performances to date, achieving 82.24% degradation of formaldehyde at room temperature, 99.99% formaldehyde degradation at 55 °C and complete retention of indoor airborne microorganisms. The complete particle retention rate (100% retention) based on the most penetrating particle size (MPPS, aerodynamic diameter ≦300 nm) of Ag@MWCNTs/Al2O3 was achieved at an only 35.60% pressure drop compared with the pristine Al2O3 filter, leading to the highest quality factor (Qf) ever reported. Furthermore, the Ag@MWCNTs/Al2O3 hybrid filter showed excellent water repellency (water contact angle of 139.6 ± 2.9°), prolonging the service life of the filters and improving the air purification efficiency. The novel Ag@MWCNTs/Al2O3 hybrid filter exhibits remarkable air purification performance in both laboratory synthetic conditions as well as in the "real world" and shows great promise as an effective single replacement for multiple layers of air purifying filters.

Amphiphobic Polytetrafluoroethylene Membranes for Efficient Organic Aerosol Removal.

Polytetrafluoroethylene (PTFE) membrane is an extensively used air filter, but its oleophilicity leads to severe fouling of the membrane surface due to organic aerosol deposition. Herein, we report the fabrication of a new amphiphobic 1H,1H,2H,2H-perfluorodecyl acrylate (PFDAE)-grafted ZnO@PTFE membrane with enhanced antifouling functionality and high removal efficiency. We use atomic-layer deposition (ALD) to uniformly coat a layer of nanosized ZnO particles onto porous PTFE matrix to increase surface area and then subsequently graft PFDAE with plasma. Consequently, the membrane surface showed both superhydrophobicity and oleophobicity with a water contact angle (WCA) and an oil contact angle (OCA) of 150° and 125°, respectively. The membrane air permeation rate of 513 (m(3) m(-2) h(-1) kPa(-1)) was lower than the pristine membrane rate of 550 (m(3) m(-2) h(-1) kPa(-1)), which indicates the surface modification slightly decreased the membrane air permeation. Significantly, the filtration resistance of this amphiphobic membrane to the oil aerosol system was much lower than the initial one. Moreover, the filter exhibited exceptional organic aerosol removal efficiencies that were greater than 99.5%. These results make the amphiphobic PTFE membranes very promising for organic aerosol-laden air-filtration applications.

Unusual Air Filters with Ultrahigh Efficiency and Antibacterial Functionality Enabled by ZnO Nanorods.

Porous membranes/filters that can remove airborne fine particulates, for example, PM2.5, with high efficiency at low energy consumption are of significant interest. Herein, we report on the fabrication of a new class of unusual superior air filters with ultrahigh efficiency and an interesting antibacterial functionality. We use atomic layer deposition (ALD) to uniformly seed ZnO on the surface of expanded polytetrafluoroethylene (ePTFE) matrix, and then synthesize well-aligned ZnO nanorods with tunable widths and lengths from the seeds under hydrothermal conditions. The presence of ZnO nanorods reduces the effective pore sizes of the ePTFE filters at little expense of energy consumption. As a consequence, the filters exhibit exceptional dust removal efficiencies greater than 99.9999% with much lower energy consumption than conventional filters. Significantly, the presence of ZnO nanorods strongly inhibits the propagation of both Gram positive and negative bacteria on the filters. Therefore, the functionalized filters can potentially overcome the inherent limitation in the trade-off effect and imply their superiority for controlling indoor air quality.

Toluene-assisted synthesis of RHO-type zeolitic imidazolate frameworks: synthesis and formation mechanism of ZIF-11 and ZIF-12.

Toluene was discovered as the structure template for the synthesis of large-cage RHO-type zeolitic imidazolate frameworks (ZIF-11 and ZIF-12) in an alcohol-based solution where benzimidazole-toluene interactions play a decisive structure-directing role; otherwise it leads to small-cage SOD-type ZIF-7 and ZIF-9 without toluene. The specific π-π interactions make toluene molecules adopt a specific and oriented arrangement in the unit cell. XRD intensity of the (100) plane is strongly dependent on the amount of toluene: apparent intensity degradation is observed after removing toluene by solvent exchange or thermal treatment, and the peak intensity is recoverable by filling of the pores with toluene vapor. More-polar methanol as compared to ethanol is favorable for the formation of RHO-type ZIFs due to the enhanced interactions between toluene and imidazolate linkers.