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1.
Proc Natl Acad Sci U S A ; 119(32): e2203937119, 2022 Aug 09.
Artigo em Inglês | MEDLINE | ID: mdl-35914127

RESUMO

Carbon dioxide utilization for enhanced metal recovery (EMR) during mineralization has been recently developed as part of CCUS (carbon capture, utilization, and storage). This paper describes fundamental studies on integrating CO2 mineralization and concurrent selective metal extraction from natural olivine. Nearly 90% of nickel and cobalt extraction and mineral carbonation efficiency are achieved in a highly selective, single-step process. Direct aqueous mineral carbonation releases Ni2+ and Co2+ into aqueous solution for subsequent recovery, while Mg2+ and Fe2+ simultaneously convert to stable mineral carbonates for permanent CO2 storage. This integrated process can be completed in neutral aqueous solution. Introduction of a metal-complexing ligand during mineral carbonation aids the highly selective extraction of Ni and Co over Fe and Mg. The ligand must have higher stability for Ni-/Co- complex ions compared with the Fe(II)-/Mg- complex ions and divalent metal carbonates. This single-step process with a suitable metal-complexing ligand is robust and utilizes carbonation processes under various kinetic regimes. This fundamental study provides a framework for further development and successful application of direct aqueous mineral carbonation with concurrent EMR. The enhanced metal extraction and CO2 mineralization process may have implications for the clean energy transition, CO2 storage and utilization, and development of new critical metal resources.

2.
J Environ Manage ; 370: 122782, 2024 Oct 05.
Artigo em Inglês | MEDLINE | ID: mdl-39369521

RESUMO

The impact of Low Carbon Pilot Policies (LCPPs) on carbon reduction and energy efficiency has been extensively studied. However, the potential of these policies to promote clean energy transition (CET) in rural households remains underexplored. This article constructed a staggered-DID model using data from the China Family Panel Studies (CFPS) to investigate the impact and mechanisms of LCPPs on rural households' CET. The findings indicate that LCPPs significantly enhance the CET among rural households. Moreover, the effects of LCPPs vary across cities, while differences within communities and households are less pronounced. Mechanism analysis reveals that LCPPs facilitate rural households' CET through income effects, infrastructure improvements, and enhanced low-carbon awareness. Notably, the income and low-carbon awareness effects are heterogeneous. Additionally, LCPPs have increased rural households' expenditures on home-cooked meals. We estimate the average fixed cost of the CET for rural households to be approximately $404.495. These insights provide valuable empirical evidence that can guide other countries and regions in promoting CET in rural areas.

3.
J Environ Manage ; 366: 121899, 2024 Aug.
Artigo em Inglês | MEDLINE | ID: mdl-39047430

RESUMO

Developing clean energy is a key pathway and an inevitable choice for achieving the goals of carbon peak and carbon neutrality. From a global perspective, technology is increasingly affecting the trajectory of energy transition, driving clean energy into a stage of rapid development. Therefore, this paper focuses on exploring the dynamic evolutionary characteristics of clean energy transitions driven by different productivity. Using panel data from 171 economies from 1990 to 2019, this paper systematically examines the impact of Total Factor Productivity (TFP) and Green Total Factor Productivity (GTFP) on clean energy transitions. The empirical results indicate that both TFP and GTFP positively impact clean energy transition. Specifically, clean energy consumption increases by 3.35% and 6.03%with a one standard deviation change in TFP and GTFP respectively. Upon decomposing TFP and GTFP, it was found that Green Efficiency Change (GECH) and Green Technical Change (GHCH), especially GECH, are the main factors driving the clean energy transition. Heterogeneity analysis shows that, in developed economies, GTFP has a larger positive impact on clean energy transition than TFP. Furthermore, GTFP demonstrates a significant positive impact on the clean energy transition both before and after the 2008 financial crisis, whereas TFP's positive impact is only evident before the crisis. Our findings emphasize the social benefits of further investments in GTFP.


Assuntos
Eficiência
4.
Environ Sci Technol ; 57(16): 6494-6505, 2023 04 25.
Artigo em Inglês | MEDLINE | ID: mdl-37040514

RESUMO

Industrial parks are emerging priorities for carbon mitigation. Here we analyze air quality, human health, and freshwater conservation co-benefits of decarbonizing the energy supply of 850 China's industrial parks. We examine a clean energy transition including early retirement of coal-fired facilities and subsequent replacement with grid electricity and onsite energy alternatives (municipal solid waste-to-energy, rooftop photovoltaic, and distributed wind power). We find that such a transition would reduce greenhouse gas emissions by 41% (equal to 7% of 2014 national CO2 equivalent emissions); emissions of SO2 by 41%, NOx by 32%, and PM2.5 by 43% and freshwater consumption by 20%, relative to a 2030 baseline scenario. Based on modeled air pollutant concentrations, we estimate such a clean energy transition will result in ∼42,000 avoided premature deaths annually due to reduced ambient PM2.5 and ozone exposure. Costs and benefits are monetized including technical costs of changes in equipment and energy use and societal benefits resulting from improvements in human health and reductions of climate impacts. We find that decarbonizing industrial parks brings annual economic benefits of US$30-156 billion in 2030. A clean energy transition in China's industrial parks thus provides both environmental and economic benefits.


Assuntos
Poluentes Atmosféricos , Poluição do Ar , Humanos , Carbono , Poluentes Atmosféricos/análise , Poluição do Ar/análise , Material Particulado/análise , China , Carvão Mineral
5.
Environ Int ; 170: 107599, 2022 12.
Artigo em Inglês | MEDLINE | ID: mdl-36323065

RESUMO

The society has high concerns on the inequality that people are disproportionately exposed to ambient air pollution, but with more time spent indoors, the disparity in the total exposure considering both indoor and outdoor exposure has not been explored; and with the socioeconomical development and efforts in fighting against air pollution, it is unknown how the exposure inequality changed over time. Based on the city-level panel data, this study revealed the Concentration Index (C) in ambient PM2.5 exposure inequality was positive, indicating the low-income group exposed to lower ambient PM2.5; however, the total PM2.5 exposure was negatively correlated with the income, showing a negative C value. The low-income population exposed to high PM2.5 associated with larger contributions of indoor exposure from the residential emissions. The total PM2.5 exposure caused 1.13 (0.63-1.73) million premature deaths in 2019, with only 14 % were high-income population. The toughest-ever air pollution countermeasures have reduced ambient PM2.5 exposures effectively that, however, benefited the rich population more than the others. The transition to clean household energy sources significantly affected on indoor air quality improvements, as well as alleviation of ambient air pollution, resulting in notable reductions of the total PM2.5 exposure and especially benefiting the low-income groups. The negative C values decreased from 2000 to 2019, indicating a significantly reducing trend in the total PM2.5 exposure inequality over time.


Assuntos
Pobreza , Humanos , China
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