RESUMO
Environmental pollution is one of the most serious challenges to health in the modern world. Pollutants alter immune responses and can provoke immunotoxicity. In this Review, we summarize the major environmental pollutants that are attracting wide-ranging concern and the molecular basis underlying their effects on the immune system. Xenobiotic receptors, including the aryl hydrocarbon receptor (AHR), sense and respond to a subset of environmental pollutants by activating the expression of detoxification enzymes to protect the body. However, chronic activation of the AHR leads to immunotoxicity. KEAP1-NRF2 is another important system that protects the body against environmental pollutants. KEAP1 is a sensor protein that detects environmental pollutants, leading to activation of the transcription factor NRF2. NRF2 protects the body from immunotoxicity by inducing the expression of genes involved in detoxification, antioxidant and anti-inflammatory activities. Intervening in these sensor-response systems could protect the body from the devastating immunotoxicity that can be induced by environmental pollutants.
Assuntos
Poluentes Ambientais/efeitos adversos , Poluição Ambiental/efeitos adversos , Imunidade , Animais , Gerenciamento Clínico , Suscetibilidade a Doenças , Exposição Ambiental/efeitos adversos , Poluentes Ambientais/química , Poluentes Ambientais/imunologia , Predisposição Genética para Doença , Humanos , Hipersensibilidade/etiologia , Hipersensibilidade/metabolismo , Hipersensibilidade/prevenção & controle , Hipersensibilidade/terapia , Sistema Imunitário/imunologia , Sistema Imunitário/metabolismo , Imunização , Inativação Metabólica , Proteína 1 Associada a ECH Semelhante a Kelch/metabolismo , Metais/efeitos adversos , Metais/química , Metais/imunologia , Células Mieloides/imunologia , Células Mieloides/metabolismo , Fator 2 Relacionado a NF-E2/genética , Fator 2 Relacionado a NF-E2/metabolismo , Especificidade de Órgãos/imunologia , Material Particulado/efeitos adversos , Material Particulado/química , Material Particulado/imunologia , Hidrocarbonetos Policíclicos Aromáticos/efeitos adversos , Hidrocarbonetos Policíclicos Aromáticos/química , Polimorfismo Genético , Linfócitos T/imunologia , Linfócitos T/metabolismoRESUMO
Aryl chlorides are among the most versatile synthetic precursors, and yet inexpensive and benign chlorination techniques to produce them are underdeveloped. We propose a process to generate aryl chlorides by chloro-group transfer from chlorophenol pollutants to arenes during their mineralization, catalyzed by Cu(NO3)2/NaNO3 under aerobic conditions. A wide range of arene substrates have been chlorinated using this process. Mechanistic studies show that the Cu catalyst acts in cooperation with NOx species generated from the decomposition of NaNO3 to regulate the formation of chlorine radicals that mediate the chlorination of arenes together with the mineralization of chlorophenol. The selective formation of aryl chlorides with the concomitant degradation of toxic chlorophenol pollutants represents a new approach in environmental pollutant detoxication. A reduction in the use of traditional chlorination reagents provides another (indirect) benefit of this procedure.
Assuntos
Cloretos , Clorofenóis , Poluentes Ambientais , Poluentes Químicos da Água , Catálise , Cloretos/síntese química , Clorofenóis/química , Clorofenóis/toxicidade , Poluentes Ambientais/química , Poluentes Ambientais/toxicidade , Halogenação , Poluentes Químicos da Água/química , Poluentes Químicos da Água/toxicidadeRESUMO
Developing efficient technologies to eliminate or degrade contaminants is paramount for environmental protection. Biocatalytic decontamination offers distinct advantages in terms of selectivity and efficiency; however, it still remains challenging when applied in complex environmental matrices. The main challenge originates from the instability and difficult-to-separate attributes of fragile enzymes, which also results in issues of compromised activity, poor reusability, low cost-effectiveness, etc. One viable solution to harness biocatalysis in complex environments is known as enzyme immobilization, where a flexible enzyme is tightly fixed in a solid carrier. In the case where a reticular crystal is utilized as the support, it is feasible to engineer next-generation biohybrid catalysts functional in complicated environmental media. This can be interpreted by three aspects: (1) the highly crystalline skeleton can shield the immobilized enzyme against external stressors. (2) The porous network ensures the high accessibility of the interior enzyme for catalytic decontamination. And (3) the adjustable and unambiguous structure of the reticular framework favors in-depth understanding of the interfacial interaction between the framework and enzyme, which can in turn guide us in designing highly active biocomposites. This Review aims to introduce this emerging biocatalysis technology for environmental decontamination involving pollutant degradation and greenhouse gas (carbon dioxide) conversion, with emphasis on the enzyme immobilization protocols and diverse catalysis principles including single enzyme catalysis, catalysis involving enzyme cascades, and photoenzyme-coupled catalysis. Additionally, the remaining challenges and forward-looking directions in this field are discussed. We believe that this Review may offer a useful biocatalytic technology to contribute to environmental decontamination in a green and sustainable manner and will inspire more researchers at the intersection of the environment science, biochemistry, and materials science communities to co-solve environmental problems.
Assuntos
Enzimas Imobilizadas , Enzimas Imobilizadas/química , Enzimas Imobilizadas/metabolismo , Porosidade , Biocatálise , Poluentes Ambientais/químicaRESUMO
Water scarcity is a pressing issue experienced in numerous countries and is expected to become increasingly critical in the future. Anthropogenic activities such as mining, agriculture, industries, and domestic waste discharge toxic contaminants into natural water bodies, causing pollution. Addressing these environmental crises requires tackling the challenge of removing pollutants from water. Graphene oxide (GO), a form of graphene functionalized with oxygen-containing chemical groups, has recently garnered renewed interest due to its exceptional properties. These properties include a large surface area, mechanical stability, and adjustable electrical and optical characteristics. Additionally, surface functional groups like hydroxyl, epoxy, and carboxyl groups make GO an outstanding candidate for interacting with other materials or molecules. Because of its expanded structural diversity and enhanced overall properties, GO and its composites hold significant promise for a wide range of applications in energy storage, conversion, and environmental protection. These applications encompass hydrogen storage materials, photocatalysts for water splitting, the removal of air pollutants, and water purification. Serving as electrode materials for various lithium batteries and supercapacitors. Graphene-based materials, including graphene, graphene oxide, reduced graphene oxide, graphene polymer nanocomposites, and graphene nanoparticle metal hybrids, have emerged as valuable tools in energy and environmental remediation technologies. This review article provides an overview of the significant impact of graphene-based materials in various areas. Regarding energy-related topics, this article explores the applications of graphene-based materials in supercapacitors, lithium-ion batteries, and catalysts for fuel cells. Additionally, the article investigates recent advancements in detecting and treating persistent organic pollutants (POPs) and heavy metals using nanomaterials. The article also discusses recent developments in creating innovative nanomaterials, nanostructures, and treatment methods for addressing POPs and heavy metals in water. It aims to present the field's current state and will be a valuable resource for individuals interested in nanomaterials and related materials.
Assuntos
Poluentes Ambientais , Grafite , Metais Pesados , Nanocompostos , Humanos , Grafite/química , Lítio , Poluentes Ambientais/química , Metais Pesados/química , Água/químicaRESUMO
Polyaromatic hydrocarbons (PAHs) are the most persistent compounds that get contaminated in the soil and water. Nearly 16 PAHs was considered to be a very toxic according US protection Agency. Though its concentration level is low in the environments but the effects due to it, is enormous. Advanced Oxidation Process (AOP) is an emergent methodology towards treating such pollutants with low and high molecular weight of complex substances. In this study, sulfate radical (SO4â¾â¢) based AOP is emphasized for purging PAH from different sources. This review essentially concentrated on the mechanism of SO4â¾â¢ for the remediation of pollutants from different sources and the effects caused due to these pollutants in the environment was reduced by this mechanism is revealed in this review. It also talks about the SO4â¾â¢ precursors like Peroxymonosulfate (PMS) and Persulfate (PS) and their active participation in treating the different sources of toxic pollutants. Though PS and PMS is used for removing different contaminants, the degradation of PAH due to SO4â¾â¢ was presented particularly. The hydroxyl radical (â¢OH) mechanism-based methods are also emphasized in this review along with their limitations. In addition to that, different activation methods of PS and PMS were discussed which highlighted the performance of transition metals in activation. Also this review opened up about the degradation efficiency of contaminants, which was mostly higher than 90% where transition metals were used for activation. Especially, on usage of nanoparticles even 100% of degradation could be able to achieve was clearly showed in this literature study. This study mainly proposed the treatment of PAH present in the soil and water using SO4â¾â¢ with different activation methodologies. Particularly, it emphasized about the importance of treating the PAH to overcome the risk associated with the environment and humans due to its contamination.
Assuntos
Recuperação e Remediação Ambiental , Oxirredução , Hidrocarbonetos Policíclicos Aromáticos , Sulfatos , Sulfatos/química , Sulfatos/análise , Hidrocarbonetos Policíclicos Aromáticos/análise , Hidrocarbonetos Policíclicos Aromáticos/química , Recuperação e Remediação Ambiental/métodos , Poluentes Ambientais/química , Poluentes Ambientais/análiseRESUMO
Carbon material modification and defect engineering are indispensable for bolstering the photocatalytic effectiveness of bismuth halide oxide (BiOX). In this study, a novel porous and defect-rich Ar-CB-2 photocatalyst was synthesized for emerging pollutants degradation. Leveraging the interfacial coupling effect of multi-walled carbon nanotubes (MWCNTs), we expanded the absorption spectrum of BiOI nanosheets and significantly suppressed the recombination of charge carriers. Introducing defects via Argon (Ar) plasma-etching further bolstered the adsorption efficacy and electron transfer properties of photocatalyst. In comparison to the pristine BiOI and CB-2, the Ar-CB-2 photocatalyst demonstrated superior photodegradation efficiency, with the first-order reaction rates for the photodegradation of tetracycline (TC) and bisphenol A (BPA) increasing by 2.83 and 4.53 times, respectively. Further probe experiments revealed that the steady-state concentrations of ·O2- and 1O2 in the Ar-CB-2/light system were enhanced by a factor of 1.67 and 1.28 compared to CB-2/light system. This result confirmed that the porous and defect-rich structure of Ar-CB-2 inhibited electron-hole recombination and boosted photocatalyst-oxygen interaction, swiftly transforming O2 into active oxygen species, thus accelerating their production. Furthermore, the possible degradation pathways for TC and BPA in the Ar-CB-2/light system were predicted. Overall, these findings offered a groundbreaking approach to the development of highly effective photocatalysts, capable of swiftly breaking down emerging pollutants.
Assuntos
Argônio , Compostos Benzidrílicos , Bismuto , Nanotubos de Carbono , Fenóis , Fotólise , Bismuto/química , Nanotubos de Carbono/química , Catálise , Porosidade , Fenóis/química , Compostos Benzidrílicos/química , Argônio/química , Tetraciclina/química , Poluentes Químicos da Água/química , Poluentes Ambientais/química , Processos Fotoquímicos , Gases em Plasma/químicaRESUMO
BACKGROUND: The family of perfluoroalkyl and polyfluoroalkyl substances (PFAS) raised concern for their proven bioaccumulation and persistence in the environment and animals as well as for their hazardous health effects. As a result, new congeners of PFAS have rapidly replaced the so-called "old long-chain PFAS" (mainly PFOA and PFOS), currently out-of-law and banned by most countries. These compounds derive from the original structure of "old long-chain PFAS", by cutting or making little conformational changes to their structure, thus obtaining new molecules with similar industrial applications. The new congeners were designed to obtain "safer" compounds. Indeed, old-long-chain PFAS were reported to exert thyroid disruptive effects in vitro, and in vivo in animals and humans. However, shreds of evidence accumulated so far indicate that the "restyling" of the old PFAS leads to the production of compounds, not only functionally similar to the previous ones but also potentially not free of adverse health effects and bioaccumulation. Studies aimed at characterizing the effects of new-PFAS congeners on thyroid function indicate that some of these new-PFAS congeners showed similar effects. PURPOSE: The present review is aimed at providing an overview of recent data regarding the effects of novel PFAS alternatives on thyroid function. RESULTS AND CONCLUSIONS: An extensive review of current legislation and of the shreds of evidence obtained from in vitro and in vivo studies evaluating the effects of the exposure to novel PFOA and PFOS alternatives, as well as of PFAS mixture on thyroid function will be provided.
Assuntos
Ácidos Alcanossulfônicos , Caprilatos , Disruptores Endócrinos , Fluorocarbonos , Glândula Tireoide , Fluorocarbonos/química , Humanos , Animais , Caprilatos/química , Ácidos Alcanossulfônicos/química , Glândula Tireoide/efeitos dos fármacos , Disruptores Endócrinos/química , Indústria Química , Poluentes Ambientais/toxicidade , Poluentes Ambientais/químicaRESUMO
Per- and poly-fluorinated compounds constitute a wide group of fluorocarbon chemicals with widespread industrial applications, ranging from non-stick coating in cookware to water surfactants, from fire-fighting foams to water-repellent coatings on textiles. Presently, over 12,000 PFAS are known worldwide. In recent years, extensive research has focused on investigating the biological effects of these molecules on various organisms, including humans. Here, we conducted in silico simulations to examine the potential binding of a representative selection of PFAS to various human proteins known to be involved in chemical transportation and accumulation processes. Specifically, we targeted human serum albumin (HSA), transthyretin (TTR), thyroxine binding protein (TBG), fatty acid binding proteins (FABPs), organic anion transporters (OATs), aiming to assess the potential for bioaccumulation. Molecular docking simulations were employed for this purpose, supplemented by molecular dynamics (MD) simulations to account for protein flexibility, when necessary. Our findings indicate that so-called "legacy PFAS" such as PFOA or PFOS exhibit a higher propensity for interaction with the analysed human protein targets compared to newly formulated PFAS, characterised by higher branching and hydrophilicity, and possibly a higher accumulation in the human body.
Assuntos
Simulação por Computador , Fluorocarbonos , Simulação de Acoplamento Molecular , Simulação de Dinâmica Molecular , Humanos , Fluorocarbonos/química , Pré-Albumina/metabolismo , Pré-Albumina/química , Albumina Sérica Humana/química , Albumina Sérica Humana/metabolismo , Ligação Proteica , Poluentes Ambientais/química , Poluentes Ambientais/toxicidade , Poluentes Ambientais/metabolismoRESUMO
Recent research [Wang et al., Nature 581, 184-189 (2020)] indicates nitric acid (NA) can participate in sulfuric acid (SA)-ammonia (NH3) nucleation in the clean and cold upper free troposphere, whereas NA exhibits no obvious effects at the boundary layer with relatively high temperatures. Herein, considering that an SA-dimethylamine (DMA) nucleation mechanism was detected in megacities [Yao et al., Science 361, 278-281 (2018)], the roles of NA in SA-DMA nucleation are investigated. Different from SA-NH3 nucleation, we found that NA can enhance SA-DMA-based particle formation rates in the polluted atmospheric boundary layer, such as Beijing in winter, with the enhancement up to 80-fold. Moreover, we found that NA can promote the number concentrations of nucleation clusters (up to 27-fold) and contribute 76% of cluster formation pathways at 280 K. The enhancements on particle formation by NA are critical for particulate pollution in the polluted boundary layer with relatively high NA and DMA concentrations.
Assuntos
Amônia/química , Dimetilaminas/química , Poluentes Ambientais/química , Poluição Ambiental/análise , Ácido Nítrico/química , Ácidos Sulfúricos/química , Atmosfera , Modelos Químicos , TermodinâmicaRESUMO
Iron-nanoparticles (Fe-NPs) are increasingly been utilized in environmental applications due to their efficacy and strong catalytic activities. The novelty of nanoparticle science had attracted many researchers and especially for their green synthesis, which can effectively reuse biological resources during the polymerization reactions. Thus, the synthesis of Fe-NPs utilizing plant extracts could be considered as the eco-friendly, simple, rapid, energy-efficient, sustainable, and cost-effective. The green synthesis route can be recognized as a practical, valuable, and economically effective alternative for large-scale production. During the production process, some biomolecules present in the extracts undergo metal salts reduction, which can serve as both a capping and reducing mechanism, enhancing the reactivity and stability of green-synthesized Fe-NPs. The diversity of species provided a wide range of potential sources for green synthesis of Fe-NPs. With improved understanding of the specific biomolecules involved in the bioreduction and stabilization processes, it will become easier to identify and utilize new, potential plant materials for Fe-NPs synthesis. Newly synthesized Fe-NPs require different characterization techniques such as transmission electron microscope, ultraviolet-visible spectrophotometry, and X-ray absorption fine structure, etc, for the determination of size, composition, and structure. This review described and assessed the recent advancements in understanding green-synthesized Fe-NPs derived from plant-based material. Detailed information on various plant materials suitable of yielding valuable biomolecules with potential diverse applications in environmental safety. Additionally, this review examined the characterization techniques employed to analyze Fe-NPs, their stability, accumulation, mobility, and fate in the environment. Holistically, the review assessed the applications of Fe-NPs in remediating wastewaters, organic residues, and inorganic contaminants. The toxicity of Fe-NPs was also addressed; emphasizing the need to refine the synthesis of green Fe-NPs to ensure safety and environmental friendliness. Moving forward, the future challenges and opportunities associated with the green synthesis of Fe-NPs would motivate novel research about nanoparticles in new directions.
Assuntos
Poluentes Ambientais , Química Verde , Ferro , Nanopartículas Metálicas , Extratos Vegetais , Química Verde/métodos , Nanopartículas Metálicas/química , Ferro/química , Poluentes Ambientais/química , Extratos Vegetais/química , Recuperação e Remediação Ambiental/métodosRESUMO
The efficient degradation of organic pollutants in diverse environmental matrices can be achieved through the synergistic application of piezo-catalysis and photocatalysis. The focus of this study is on understanding the fundamental principles and mechanisms that govern the collaborative action of piezoelectric and photocatalytic materials. Piezoelectric nanomaterials, under mechanical stress, generate piezo-potential, which, when coupled with photocatalysts, enhances the generation and separation of charge carriers. The resulting cascade of redox reactions promotes the degradation of a wide spectrum of organic pollutants. The comprehensive investigation involves a variety of experimental techniques, including advanced spectroscopy and microscopy, to elucidate the intricate interplay between mechanical and photoinduced processes. The influence of key parameters, such as material composition, morphology, and external stimuli on the catalytic performance, is systematically explored. This study contributes to the increasing knowledge of environmental remediation and lays the foundation for the development of advanced technologies using piezo and photocatalysis for sustainable pollutant removal.
Assuntos
Recuperação e Remediação Ambiental , Processos Fotoquímicos , Catálise , Poluentes Ambientais/química , Nanoestruturas/químicaRESUMO
Bentonite-based composites have been widely utilized in the removal of various pollutants due to low cost, environmentally friendly, ease-to-operate, whereas the recent advances concerning the application of bentonite-based composites in environmental remediation were not available. Herein, the modification (i.e., acid/alkaline washing, thermal treatment and hybrids) of bentonite was firstly reviewed; Then the recent advances of adsorption of environmental concomitants (e.g., organic (dyes, microplastics, phenolic and other organics) and inorganic pollutants (heavy metals, radionuclides and other inorganic pollutants)) on various bentonite-based composites were summarized in details. Meanwhile, the effect of environmental factors and interaction mechanism between bentonite-based composites and contaminants were also investigated. Finally, the conclusions and prospective of bentonite-based composites in the environmental remediation were proposed. It is demonstrated that various bentonite-based composites exhibited the high adsorption/degradation capacity towards environmental pollutants under the specific conditions. The interaction mechanism involved the mineralization, physical/chemical adsorption, co-precipitation and complexation. This review highlights the effect of different functionalization of bentonite-based composites on their adsorption capacity and interaction mechanism, which is expected to be helpful to environmental scientists for applying bentonite-based composites into practical environmental remediation.
Assuntos
Bentonita , Recuperação e Remediação Ambiental , Bentonita/química , Recuperação e Remediação Ambiental/métodos , Adsorção , Metais Pesados/química , Poluentes Ambientais/químicaRESUMO
One of the major issues of modern society is water contamination with different organic, inorganic, and contaminants bacteria. Finding cost-effective and efficient materials and methods for water treatment and environment remediation is among the scientists' most important considerations. Hollow-structured nanomaterials, including hollow fiber membranes, hollow spheres, hollow nanoboxes, etc., have shown an exciting capability for wastewater refinement approaches, including membrane technology, adsorption, and photocatalytic procedure due to their extremely high specific surface area, high porosity, unique morphology, and low density. Diverse hollow nanostructures could potentially eliminate organic contaminants, including dyes, antibiotics, oil/water emulsions, pesticides, and other phenolic compounds, inorganic pollutants, such as heavy metal ions, salts, phosphate, bromate, and other ions, and bacteria contaminations. Here, a comprehensive overview of hollow nanostructures' fabrication and modification, water contaminant classification, and recent studies in the water treatment field using hollow-structured nanomaterials with a comparative attitude have been provided, indicating the privilege abd detriments of this class of nanomaterials. Eventually, the future outlook of employing hollow nanomaterials in water refinery systems and the upcoming challenges arising in scaling up are also propounded.
Assuntos
Poluentes Ambientais , Metais Pesados , Nanoestruturas , Poluentes Químicos da Água , Purificação da Água , Poluentes Ambientais/química , Nanoestruturas/química , Purificação da Água/métodos , Metais Pesados/química , Adsorção , Íons , Poluentes Químicos da Água/químicaRESUMO
Specialized chemicals are used for intensifying food production, including boosting meat and crop yields. Among the applied formulations, antibiotics and pesticides pose a severe threat to the natural balance of the ecosystem, as they either contribute to the development of multidrug resistance among pathogens or exhibit ecotoxic and mutagenic actions of a persistent character. Recently, cold atmospheric pressure plasmas (CAPPs) have emerged as promising technologies for degradation of these organic pollutants. CAPP-based technologies show eco-friendliness and potency for the removal of organic pollutants of diverse chemical formulas and different modes of action. For this reason, various types of CAPP-based systems are presented in this review and assessed in terms of their constructions, types of discharges, operating parameters, and efficiencies in the degradation of antibiotics and persistent organic pollutants. Additionally, the key role of reactive oxygen and nitrogen species (RONS) is highlighted. Moreover, optimization of the CAPP operating parameters seems crucial to effectively remove contaminants. Finally, the CAPP-related paths and technologies are further considered in terms of biological and environmental effects associated with the treatments, including changes in antibacterial properties and toxicity of the exposed solutions, as well as the potential of the CAPP-based strategies for limiting the spread of multidrug resistance.
Assuntos
Pressão Atmosférica , Gases em Plasma , Gases em Plasma/química , Poluentes Ambientais/química , Indústria Alimentícia , Antibacterianos/química , Antibacterianos/farmacologia , Espécies Reativas de Oxigênio/metabolismo , Compostos Orgânicos/químicaRESUMO
Bioremediation uses the degradation abilities of microorganisms and other organisms to remove harmful pollutants that pollute the natural environment, helping return it to a natural state that is free of harmful substances. Organism-derived enzymes can degrade and eliminate a variety of pollutants and transform them into non-toxic forms; as such, they are expected to be used in bioremediation. However, since enzymes are proteins, the low operational stability and catalytic efficiency of free enzyme-based degradation systems need improvement. Enzyme immobilization methods are often used to overcome these challenges. Several enzyme immobilization methods have been applied to improve operational stability and reduce remediation costs. Herein, we review recent advancements in immobilized enzymes for bioremediation and summarize the methods for preparing immobilized enzymes for use as catalysts and in pollutant degradation systems. Additionally, the advantages, limitations, and future perspectives of immobilized enzymes in bioremediation are discussed.
Assuntos
Biodegradação Ambiental , Poluentes Ambientais , Enzimas Imobilizadas , Enzimas Imobilizadas/química , Enzimas Imobilizadas/metabolismo , Poluentes Ambientais/metabolismo , Poluentes Ambientais/química , Reatores Biológicos , Substâncias Perigosas/metabolismoRESUMO
Persistent organic pollutants (POPs) exist widely in the environment and place significant impact on human health by bioaccumulation. Efficient recognition of POPs and their removal are highly challenging tasks because their specific structures interact often very weakly with the capture materials. Herein, a molecular nanocage (1) is studied as an efficient sensing and sorbent material for POPs, which is demonstrated by a representative and stable perfluorooctane sulfonate (PFOS) substrate containing a hydrophilic sulfonic group and a hydrophobic fluoroalkyl chain. A highly sensitive and unusual turn-on fluorescence response within 10 s and a 97% total removal of PFOS from water in 20 min have been achieved owing to the strong host-guest interactions between 1 and PFOS. The binding constant of 1 to PFOS is 2 orders of magnitude higher than state-of-the-art adsorbents for PFOS and thus represents a new benchmark material for the recognition and removal of PFOS. The host-guest interaction has been elucidated by solid-state NMR spectroscopy and single-crystal X-ray diffraction, which provide key insights at a molecular level for the design of new advanced sensing/sorbent materials for POPs.
Assuntos
Ácidos Alcanossulfônicos , Poluentes Ambientais , Fluorocarbonos , Poluentes Químicos da Água , Humanos , Poluentes Orgânicos Persistentes , Poluentes Químicos da Água/química , Adsorção , Poluentes Ambientais/química , Água , Fluorocarbonos/química , Ácidos Alcanossulfônicos/químicaRESUMO
Over the last 100-120 years, due to the ever-increasing importance of fluorine-containing compounds in modern technology and daily life, the explosive development of the fluorochemical industry led to an enormous increase of emission of fluoride ions into the biosphere. This made it more and more important to understand the biological activities, metabolism, degradation, and possible environmental hazards of such substances. This comprehensive and critical review focuses on the effects of fluoride ions and organofluorine compounds (mainly pharmaceuticals and agrochemicals) on human health and the environment. To give a better overview, various connected topics are also discussed: reasons and trends of the advance of fluorine-containing pharmaceuticals and agrochemicals, metabolism of fluorinated drugs, withdrawn fluorinated drugs, natural sources of organic and inorganic fluorine compounds in the environment (including the biosphere), sources of fluoride intake, and finally biomarkers of fluoride exposure.
Assuntos
Poluentes Ambientais/química , Flúor/química , Poluição Ambiental , Hidrocarbonetos Fluorados/químicaRESUMO
Covalent organic frameworks (COFs) have attracted increasing research interest due to their intriguing topological structures and fascinating properties. Diverse COFs with different shapes and sizes are developed by the design of appropriate building blocks. However, the heteroporous COFs to date are still in their infancy due to the relatively limited configuration of precursors. Herein, it is ingeniously designed and synthesized a new K-shaped "two-in-one" building unit (3',6'-bis(4-(5,5-dimethyl-1,3-dixoan-2-yl)phenyl)-[1,1':2',1"-terphenyl]-4,4"-diamine, BPTD), thus realizing the construction of triangular dual microporous COF (BPTD-COF) via self-polycondensation of the K-shaped monomer. The super micropore (0.76 nm) of BPTD-COF endows the higher density of amine activity sites, while the other aperture size (1.35 nm) meets the need for accommodating cationic dyes (rhodamine B, methylene blue), thus BPTD-COF displays a distinctive selective adsorption for cationic dyes with good reusability.
Assuntos
Aminas , Estruturas Metalorgânicas , Estruturas Metalorgânicas/síntese química , Estruturas Metalorgânicas/química , Aminas/química , Corantes/química , Poluentes Ambientais/química , Recuperação e Remediação Ambiental , AdsorçãoRESUMO
The growing global concern about environmental threats due to environmental pollution requires the development of environmentally friendly and efficient removal/detection materials and methods. Porphyrin/phthalocyanine (Por/Pc) based porous organic polymers (POPs) as a newly emerging porous material are prepared through polymerizing building blocks with different structures. Benefiting from the high porosity, adjustable pore structure, and enzyme-like activities, the Por/Pc-POPs can be the ideal platform to study the removal and detection of pollutants. However, a systematic summary of their application in environmental treatment is still lacking to date. In this review, the development of various Por/Pc-POPs for pollutant removal and detection applications over the past decade was systematically addressed for the first time to offer valuable guidance on environmental remediation through the utilization of Por/Pc-POPs. This review is divided into two sections (pollutants removal and detection) focusing on Por/Pc-POPs for organic, inorganic, and gaseous pollutants adsorption, photodegradation, and chemosensing, respectively. The related removal and sensing mechanisms are also discussed, and the methods to improve removal and detection efficiency and selectivity are also summarized. For the future practical application of Por/Pc-POPs, this review provides the emerging research directions and their application possibility and challenges in the removal and detection of pollutants.
Assuntos
Poluentes Ambientais , Porfirinas , Poluentes Ambientais/química , Porosidade , Polímeros/químicaRESUMO
Modern society has increasingly a diffusion of pollutants and emerging contaminants (e.g., different types of chemicals and endocrine disruptors in pharmaceuticals, pesticides, household cleaning, and personal care products, etc.) that have detrimental effects on the environment (atmosphere, hydrosphere, biosphere and anthroposphere) and also generate diseases and disorders on the people health. Environmental science requires efforts in the detection and elimination of manifold pollutants and emerging pollutants with appropriate product and process technologies. This study aims to analyze different paths of treatment technologies to investigate their evolution and predict new directions of promising technological trajectories to support the removal of contaminants directed to reach, whenever possible, sustainable development objectives. The work is mainly devoted to wastewater treatment technologies. A proposed model analyzes the evolution of patents (proxy of innovation and new technology) on publications (proxy of science and knowledge advances) to quantify the relative growth rate of new trajectories of technologies to remove pollutants and emerging contaminants. Results reveal that new directions of treatment technologies having an accelerated rate of growth are (in decreasing order): biochar and reverse osmosis in physical-based technologies, coagulation, and disinfection water treatments in chemical-based technologies and anaerobic processes in biological-based technologies. Other main technologies, such as carbon nanotubes and advanced oxidation processes, seem to be in the initial phase of development and need learning by using processes and further science and technology advances to be implemented as effective treatments and cost-effective methods. The results here show similar trends to global market revenue in water and wastewater treatment technologies. These findings bring us to the main information to extend the knowledge about new directions of technologies for the treatment and/or elimination of pollutants and microorganisms in order to support decisions of policymakers towards goals of sustainable development by reducing environmental degradation and people health disorders.