Synthesis of the new, cubane-like W3S4Co cluster core. Completion of the homologous series [(eta5-Cp')3M3S4Co(CO)] (M = Cr, Mo, W).
Inorg Chem
; 43(11): 3327-8, 2004 May 31.
Article
em En
| MEDLINE
| ID: mdl-15154790
ABSTRACT
Reaction between the cluster salts [(eta(5)-Cp')(3)M(3)S(4)][pts] (M = Mo, W; Cp' = methylcyclopentadienyl; pts = p-toluenesulfonate) and [Co(2)(CO)(8)] yielded the electroneutral clusters [(eta(5)-Cp')(3)M(3)S(4)Co(CO)]. The molecular structure of [(eta(5)-Cp')(3)W(3)S(4)Co(CO)] was determined by single-crystal X-ray diffraction methods. The unprecedented 60 electron W(3)S(4)Co cluster completes a homologous series of heterobimetallic clusters, [(eta(5)-Cp')(3)M(3)S(4)Co(CO)] (M = Cr, Mo, W), containing a cubane-like core motif.
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Coleções:
01-internacional
Base de dados:
MEDLINE
País/Região como assunto:
Cuba
Idioma:
En
Revista:
Inorg Chem
Ano de publicação:
2004
Tipo de documento:
Article
País de afiliação:
Dinamarca