Direct synthesis of ester-containing indium homoenolate and its application in palladium-catalyzed cross-coupling with aryl halide.
Chem Commun (Camb)
; 47(16): 4778-80, 2011 Apr 28.
Article
em En
| MEDLINE
| ID: mdl-21412540
ABSTRACT
An efficient method for the synthesis of ester-containing indium homoenolate via a direct insertion of indium into ß-halo ester in the presence of CuI/LiCl was described. The synthetic utility of the indium homoenolate was demonstrated by palladium-catalyzed cross-coupling with aryl halides in DMA with wide functional group compatibility.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Assunto principal:
Compostos Organometálicos
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Paládio
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Cloreto de Lítio
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Cobre
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Ésteres
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Índio
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Iodetos
Idioma:
En
Revista:
Chem Commun (Camb)
Assunto da revista:
QUIMICA
Ano de publicação:
2011
Tipo de documento:
Article