4,4'-Bipyridine-cyano-acetic acid (1/2).
Acta Crystallogr Sect E Struct Rep Online
; 64(Pt 11): o2058, 2008 Oct 04.
Article
em En
| MEDLINE
| ID: mdl-21580924
ABSTRACT
Crystals of the title adduct, C(10)H(8)N(2)·2C(3)H(3)NO(2), were obtained from a methanol/water solution of cyano-acetic acid and 4,4'-bipyridine at room temperature. In the crystal structure, cyano-acetic acid and centrosymmetric 4,4'-bipyridine mol-ecules are linked by O-Hâ¯N hydrogen bonds to form three-component supra-molecular adducts. The acidic H atom is almost midway between the O and N atoms of the cyano-acetic acid and bipyridine mol-ecules, with O-H and N-H distances of 1.19â
(3) and 1.39â
(3)â
Å, respectively, so that the H-atom transfer is best regarded as partial. The three-component adducts are further inter-connected with neighboring mol-ecules by weak inter-molecular C-Hâ¯O and C-Hâ¯N hydrogen bonds and by π-π stacking inter-actions [centroid-centroid distance = 3.7200â
(11)â
Å] to generate a three-dimensional supra-molecular structure.
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1
Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Acta Crystallogr Sect E Struct Rep Online
Ano de publicação:
2008
Tipo de documento:
Article