Charge order in LuFe2O4: an unlikely route to ferroelectricity.
Phys Rev Lett
; 108(18): 187601, 2012 May 04.
Article
em En
| MEDLINE
| ID: mdl-22681119
ABSTRACT
We present the refinement of the crystal structure of charge-ordered LuFe2O4, based on single-crystal x-ray diffraction data. The arrangement of the different Fe-valence states, determined with bond-valence-sum analysis, corresponds to a stacking of charged Fe bilayers, in contrast with the polar bilayers previously suggested. This arrangement is supported by an analysis of x-ray magnetic circular dichroism spectra, which also evidences a strong charge-spin coupling. The nonpolar bilayers are inconsistent with charge order based ferroelectricity.
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01-internacional
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MEDLINE
Idioma:
En
Revista:
Phys Rev Lett
Ano de publicação:
2012
Tipo de documento:
Article
País de afiliação:
Alemanha