Evaluation of a hydrophilic ionic liquid as a salting-out phase separation agent to a water-tetrahydrofuran homogeneous system for aqueous biphasic extraction separation.
Anal Sci
; 28(6): 541-3, 2012.
Article
em En
| MEDLINE
| ID: mdl-22729039
ABSTRACT
The use of a hydrophilic ionic liquid (IL), 1-butyl-3-methylimidazolium chloride (C(4)mimCl), as a salting-out phase separation agent to a water-tetrahydrofuran homogeneous system was studied for possible applications to novel aqueous biphasic extraction separation. The IL showed a salting-out phase-separation ability. Also, differences in the polarity between the formed two phases were smaller than that when using NaCl as a salting-out agent. This result suggested that C(4)mimCl remaining in water-rich phase acts not only as a salting-out agent, but also a component of a mixed-solvent. Possible uses of C(4)mimCl/NaCl mixed salting-out agent system were also discussed.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Assunto principal:
Água
/
Cloreto de Sódio
/
Líquidos Iônicos
/
Fracionamento Químico
/
Furanos
/
Imidazóis
Tipo de estudo:
Evaluation_studies
Idioma:
En
Revista:
Anal Sci
Ano de publicação:
2012
Tipo de documento:
Article
País de afiliação:
Japão