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Stepwise construction of the Cr-Cr quintuple bond and its destruction upon axial coordination.
Huang, Yu-Lun; Lu, Duan-Yen; Yu, Hsien-Cheng; Yu, Jen-Shiang K; Hsu, Chia-Wei; Kuo, Ting-Shen; Lee, Gene-Hsiang; Wang, Yu; Tsai, Yi-Chou.
Afiliação
  • Huang YL; Department of Chemistry and Frontier Research Center on Fundamental and Applied Sciences of Matters, National Tsing Hua University, Hsinchu 30013, Taiwan.
Angew Chem Int Ed Engl ; 51(31): 7781-5, 2012 Jul 27.
Article em En | MEDLINE | ID: mdl-22730058
Give me five! Terdentate 2,6-diamidopyridyl ligands were used to stabilize the Cr-Cr quintuple bond and have made it possible to isolate and characterize not only the Cr-Cr quintuple-bonded complex, but also the mixed-valent intermediates (Cr(I) and Cr(II)), which are important species in the formation of type I quintuple-bonded complexes.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Cromo / Complexos de Coordenação Idioma: En Revista: Angew Chem Int Ed Engl Ano de publicação: 2012 Tipo de documento: Article País de afiliação: Taiwan
Texto completo
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XML
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Buscar no Google

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Cromo / Complexos de Coordenação Idioma: En Revista: Angew Chem Int Ed Engl Ano de publicação: 2012 Tipo de documento: Article País de afiliação: Taiwan