Poly[bis-(ethanol)(µ4-2,3,5,6-tetra-fluoro-benzene-1,4-di-carboxyl-ato)cadmium].
Acta Crystallogr Sect E Struct Rep Online
; 69(Pt 11): m577-8, 2013 Oct 02.
Article
em En
| MEDLINE
| ID: mdl-24454021
In the title compound, [Cd(C8F4O4)(C2H5OH)2] n , the Cd(II) cation sits on an inversion centre and is coordinated by six O atoms from four tetra-fluoro-benzene-1,4-di-carboxyl-ate anions and two ethanol mol-ecules in a distorted octa-hedral geometry. The anionic ligand is also located on an inversion centre, and connects four Cd(II) cations, generating a two-dimensional polymeric layer parallel to the ab plane. Within the layer, the ethanol mol-ecule links F and O atoms of the nearest anionic ligands via O-Hâ¯O and O-Hâ¯F hydrogen bonds. The ethyl group of the ethanol mol-ecule is disordered over two positions with an occupancy ratio of 0.567â
(10):0.433â
(10).
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1
Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Acta Crystallogr Sect E Struct Rep Online
Ano de publicação:
2013
Tipo de documento:
Article
País de afiliação:
Coréia do Sul