[Biosorption characteristics of Cu2+ by spent substrate of pleurotus oyster].
Huan Jing Ke Xue
; 35(2): 669-77, 2014 Feb.
Article
em Zh
| MEDLINE
| ID: mdl-24812963
ABSTRACT
To solve the problems of heavy metal pollution and agricultural wastes reclamation, spent substrate of pleurotus oyster was used as adsorbents to remove Cu2+ from aqueous solution. The effects of pH value, adsorption time, temperature and initial Cu2+ concentration on the adsorption behavior were determined by single factor experiments. The mechanisms were preliminarily investigated by SEM-EDX, FTIR and XRD analysis. The results of single factor experiments showed that the adsorption rate and capacity reached 74.46% and 0.7446 mg x g(-1) respectively at an adsorbent concentration of 10 g x L(-1), a pH of 6, an adsorption time of 120 min, an adsorption temperature of 30 degrees C and an initial Cu2+ concentration of 8 mg x L(-1). The experimental data fitted well with Langmuir isotherm models and R2 reached 0.994 9, indicating the adsorption was a monolayer chemisorption. SEM-EDX, FTIR and XRD analysis indicated that the adsorption process mainly depended on the physical and chemical adsorption onto the substrate surface through electrostatic attraction, complexation and coordination reaction. The -OH, -COOH and -NH were the functioning groups for Cu2+ adsorption.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Assunto principal:
Cobre
/
Pleurotus
/
Recuperação e Remediação Ambiental
Tipo de estudo:
Prognostic_studies
Limite:
Animals
Idioma:
Zh
Revista:
Huan Jing Ke Xue
Ano de publicação:
2014
Tipo de documento:
Article