Simple, chemoselective, catalytic olefin isomerization.
J Am Chem Soc
; 136(48): 16788-91, 2014 Dec 03.
Article
em En
| MEDLINE
| ID: mdl-25398144
ABSTRACT
Catalytic amounts of Co(Sal(tBu,tBu))Cl and organosilane irreversibly isomerize terminal alkenes by one position. The same catalysts effect cycloisomerization of dienes and retrocycloisomerization of strained rings. Strong Lewis bases like amines and imidazoles, and labile functionalities like epoxides, are tolerated.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Assunto principal:
Compostos Organometálicos
/
Silanos
/
Cobalto
/
Alcenos
Idioma:
En
Revista:
J Am Chem Soc
Ano de publicação:
2014
Tipo de documento:
Article
País de afiliação:
Estados Unidos