Singlet-oxygen oxidation of 5-hydroxymethylfurfural in continuous flow.
ChemSusChem
; 8(10): 1648-51, 2015 May 22.
Article
em En
| MEDLINE
| ID: mdl-25505009
ABSTRACT
Singlet-oxygen oxidation of 5-hydroxymethylfurfural (5-HMF) was performed in continuous flow mode using rose Bengal as photosensitizer. The resulting butenolide (H(2) MF) was formed selectively in high yield. The procedure proved to be scalable and applicable to related bio-based furfurals. Furthermore, preliminary data show that H(2) MF can be readily isomerized thermally to 5-hydroxy-4-keto-pentenoic acid oligomers.
Palavras-chave
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Assunto principal:
Oxigênio Singlete
/
Furaldeído
Idioma:
En
Revista:
ChemSusChem
Assunto da revista:
QUIMICA
/
TOXICOLOGIA
Ano de publicação:
2015
Tipo de documento:
Article