A triazole-bearing picket fence type nickel porphyrin as a cyanide selective allosteric host.
Chem Commun (Camb)
; 51(35): 7486-8, 2015 May 01.
Article
em En
| MEDLINE
| ID: mdl-25831467
ABSTRACT
A triazole-bearing picket fence type nickel porphyrin (1) has been synthesized as a host compound for anion binding. Among the various anionic species examined, cyanide was the only one that affected a spectral change of 1. Moreover, 1 exhibited strong homotropic positive allosterism against cyanide binding due to an electronic effect as well as multiple hydrogen bonds formed between cyanide and the triazole groups.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Assunto principal:
Porfirinas
/
Espectrofotometria
/
Triazóis
/
Cianetos
/
Metaloporfirinas
/
Níquel
Idioma:
En
Revista:
Chem Commun (Camb)
Assunto da revista:
QUIMICA
Ano de publicação:
2015
Tipo de documento:
Article