Ni-Catalyzed Borylation of Aryl Fluorides via C-F Cleavage.

Liu, Xiang-Wei; Echavarren, Javier; Zarate, Cayetana; Martin, Ruben

Liu, Xiang-Wei; Echavarren, Javier; Zarate, Cayetana; Martin, Ruben.

Afiliação

Liu XW; Institute of Chemical Research of Catalonia (ICIQ) , Av. Països Catalans 16, 43007 Tarragona, Spain.
Echavarren J; Institute of Chemical Research of Catalonia (ICIQ) , Av. Països Catalans 16, 43007 Tarragona, Spain.
Zarate C; Institute of Chemical Research of Catalonia (ICIQ) , Av. Països Catalans 16, 43007 Tarragona, Spain.
Martin R; Institute of Chemical Research of Catalonia (ICIQ) , Av. Països Catalans 16, 43007 Tarragona, Spain.

J Am Chem Soc ; 137(39): 12470-3, 2015 Oct 07.

Article em En | MEDLINE | ID: mdl-26397717

ABSTRACT

ABSTRACT

A Ni-catalyzed borylation via C-F activation is described. This protocol is distinguished by a wide scope, including unactivated fluoroarenes, without compromising its efficiency and scalability, thus representing a significant step-forward toward the implementation of C-F activation protocols.

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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: J Am Chem Soc Ano de publicação: 2015 Tipo de documento: Article País de afiliação: Espanha

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