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In Situ Raman Monitoring of Silver(I)-Aided Laser-Driven Cleavage Reaction of Cyclobutane.
Chen, Dengtai; Han, Xijiang; Du, Yunchen; Wang, Hsing-Lin; Xu, Ping.
Afiliação
  • Chen D; Department of Chemistry, Harbin Institute of Technology, Harbin, 150001, P. R. China.
  • Han X; Department of Chemistry, Harbin Institute of Technology, Harbin, 150001, P. R. China. pxu@hit.edu.cn.
  • Du Y; Department of Chemistry, Harbin Institute of Technology, Harbin, 150001, P. R. China.
  • Wang HL; Chemistry Division, Los Alamos National Laboratory, Los Alamos, NM 87545, USA.
  • Xu P; Department of Chemistry, Harbin Institute of Technology, Harbin, 150001, P. R. China. hanxijiang@hit.edu.cn.
Chemphyschem ; 17(1): 46-50, 2016 Jan 04.
Article em En | MEDLINE | ID: mdl-26510491
ABSTRACT
The cyclobutane cleavage reaction is an important process and has received continuous interest. Herein, we demonstrate the visible laser-driven cleavage reaction of cyclobutane in crystal form by using in situ Raman spectroscopy. Silver(I) coordination-induced strain and thermal effects from the laser irradiation are the two main driving forces for the cleavage of cyclobutane crystals. This work may open up a new avenue for studying cyclobutane cleavage reactions, as compared to the conventional routes using ex situ techniques.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Prata / Ciclobutanos Idioma: En Revista: Chemphyschem Assunto da revista: BIOFISICA / QUIMICA Ano de publicação: 2016 Tipo de documento: Article
Texto completo
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XML
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Prata / Ciclobutanos Idioma: En Revista: Chemphyschem Assunto da revista: BIOFISICA / QUIMICA Ano de publicação: 2016 Tipo de documento: Article