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Self-assembly of a "double dynamic covalent" amphiphile featuring a glucose-responsive imine bond.
Wu, Xin; Chen, Xuan-Xuan; Zhang, Miao; Li, Zhao; Gale, Philip A; Jiang, Yun-Bao.
Afiliação
  • Wu X; Department of Chemistry, College of Chemistry and Chemical Engineering, The MOE Key Laboratory of Spectrochemical Analysis and Instrumentation, and Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), Xiamen University, Xiamen 361005, China. ybjiang@xmu.edu.cn and Chemistry, Un
  • Chen XX; Department of Chemistry, College of Chemistry and Chemical Engineering, The MOE Key Laboratory of Spectrochemical Analysis and Instrumentation, and Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), Xiamen University, Xiamen 361005, China. ybjiang@xmu.edu.cn.
  • Zhang M; Department of Chemistry, College of Chemistry and Chemical Engineering, The MOE Key Laboratory of Spectrochemical Analysis and Instrumentation, and Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), Xiamen University, Xiamen 361005, China. ybjiang@xmu.edu.cn.
  • Li Z; Department of Chemistry, College of Chemistry and Chemical Engineering, The MOE Key Laboratory of Spectrochemical Analysis and Instrumentation, and Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), Xiamen University, Xiamen 361005, China. ybjiang@xmu.edu.cn.
  • Gale PA; Chemistry, University of Southampton, Southampton SO17 1BJ, UK.
  • Jiang YB; Department of Chemistry, College of Chemistry and Chemical Engineering, The MOE Key Laboratory of Spectrochemical Analysis and Instrumentation, and Collaborative Innovation Center of Chemistry for Energy Materials (iChEM), Xiamen University, Xiamen 361005, China. ybjiang@xmu.edu.cn.
Chem Commun (Camb) ; 52(43): 6981-4, 2016 May 19.
Article em En | MEDLINE | ID: mdl-27112284
ABSTRACT
Glucose binding via boronate ester linkages selectively triggers imine bond formation between 4-formylphenylboronic acid and octylamine, leading to the formation of vesicular aggregates in aqueous solutions. This "double dynamic covalent assembly" allows the facile selective sensing of glucose against the otherwise serious interferant fructose, without the need to resort to synthetic effort.
Assuntos

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Tensoativos / Substâncias Macromoleculares / Glucose / Iminas Idioma: En Revista: Chem Commun (Camb) Assunto da revista: QUIMICA Ano de publicação: 2016 Tipo de documento: Article

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Tensoativos / Substâncias Macromoleculares / Glucose / Iminas Idioma: En Revista: Chem Commun (Camb) Assunto da revista: QUIMICA Ano de publicação: 2016 Tipo de documento: Article