Ni-Catalyzed Carboxylation of Unactivated Alkyl Chlorides with CO2.

Börjesson, Marino; Moragas, Toni; Martin, Ruben

Börjesson, Marino; Moragas, Toni; Martin, Ruben.

Afiliação

Börjesson M; Institute of Chemical Research of Catalonia (ICIQ), The Barcelona Institute of Science and Technology , Av. Països Catalans 16, 43007 Tarragona, Spain.
Moragas T; Institute of Chemical Research of Catalonia (ICIQ), The Barcelona Institute of Science and Technology , Av. Països Catalans 16, 43007 Tarragona, Spain.
Martin R; Institute of Chemical Research of Catalonia (ICIQ), The Barcelona Institute of Science and Technology , Av. Països Catalans 16, 43007 Tarragona, Spain.

J Am Chem Soc ; 138(24): 7504-7, 2016 06 22.

Article em En | MEDLINE | ID: mdl-27269443

ABSTRACT

ABSTRACT

A catalytic carboxylation of unactivated primary, secondary, and tertiary alkyl chlorides with CO2 at atmospheric pressure is described. This protocol represents the first intermolecular cross-electrophile coupling of unactivated alkyl chlorides, thus leading to new knowledge in the cross-coupling arena.

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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: J Am Chem Soc Ano de publicação: 2016 Tipo de documento: Article País de afiliação: Espanha

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