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Rhodomentones A and B, novel meroterpenoids with unique NMR characteristics from Rhodomyrtus tomentosa.
Liu, Hong-Xin; Chen, Kai; Yuan, Yao; Xu, Zhi-Fang; Tan, Hai-Bo; Qiu, Sheng-Xiang.
Afiliação
  • Liu HX; Program for Natural Products Chemical Biology, Key Laboratory of Plant Resources Conservation and Sustainable Utilization, South China Botanical Garden, Chinese Academy of Sciences, Guangzhou 510650, China. tanhaibo@scbg.ac.cn sxqiu@scbg.ac.cn and State Key Laboratory of Applied Microbiology Souther
  • Chen K; School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, China.
  • Yuan Y; Program for Natural Products Chemical Biology, Key Laboratory of Plant Resources Conservation and Sustainable Utilization, South China Botanical Garden, Chinese Academy of Sciences, Guangzhou 510650, China. tanhaibo@scbg.ac.cn sxqiu@scbg.ac.cn.
  • Xu ZF; Program for Natural Products Chemical Biology, Key Laboratory of Plant Resources Conservation and Sustainable Utilization, South China Botanical Garden, Chinese Academy of Sciences, Guangzhou 510650, China. tanhaibo@scbg.ac.cn sxqiu@scbg.ac.cn.
  • Tan HB; Program for Natural Products Chemical Biology, Key Laboratory of Plant Resources Conservation and Sustainable Utilization, South China Botanical Garden, Chinese Academy of Sciences, Guangzhou 510650, China. tanhaibo@scbg.ac.cn sxqiu@scbg.ac.cn.
  • Qiu SX; Program for Natural Products Chemical Biology, Key Laboratory of Plant Resources Conservation and Sustainable Utilization, South China Botanical Garden, Chinese Academy of Sciences, Guangzhou 510650, China. tanhaibo@scbg.ac.cn sxqiu@scbg.ac.cn.
Org Biomol Chem ; 14(30): 7354-60, 2016 Jul 26.
Article em En | MEDLINE | ID: mdl-27405792
ABSTRACT
Two novel meroterpenoids, rhodomentones A and B bearing an unprecedented caryophyllene-conjugated oxa-spiro[5.8] tetradecadiene skeleton, were isolated from the leaves of Rhodomyrtus tomentosa. Their structures with unique NMR characteristics were determined by extensive spectroscopic analysis, single-crystal X-ray diffraction, quantum molecular calculation, chemical transformation as well as total synthesis.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Sesquiterpenos / Compostos de Espiro / Terpenos / Extratos Vegetais / Myrtaceae Tipo de estudo: Prognostic_studies Limite: Humans Idioma: En Revista: Org Biomol Chem Assunto da revista: BIOQUIMICA / QUIMICA Ano de publicação: 2016 Tipo de documento: Article
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Sesquiterpenos / Compostos de Espiro / Terpenos / Extratos Vegetais / Myrtaceae Tipo de estudo: Prognostic_studies Limite: Humans Idioma: En Revista: Org Biomol Chem Assunto da revista: BIOQUIMICA / QUIMICA Ano de publicação: 2016 Tipo de documento: Article