Cellulose-derived carbon aerogels supported goethite (α-FeOOH) nanoneedles and nanoflowers for electromagnetic interference shielding.

ABSTRACT

We describe a rapid and facile chemical precipitation method to grow goethite (α-FeOOH) nanoneedles and nanoflowers on the carbon aerogels which was obtained from the pyrolysis of cellulose aerogels. When evaluated as electromagnetic interference (EMI) shielding materials, the α-FeOOH/cellulose-derived carbon aerogels composite displays the highest SEtotal value of 34.0dB at the Fe3+/Fe2+ concentration of 0.01M, which is about 4.8 times higher than that of the individual α-FeOOH (5.9dB). When the higher or lower Fe3+/Fe2+ concentrations were used, the EMI shielding performance deterioration occurred. The integration of α-FeOOH with the carbon aerogels transforms the reflection-dominant mechanism for α-FeOOH into the adsorption-dominant mechanism for the composite. The adsorption-dominant mechanism undoubtedly makes contribution to alleviating secondary radiation, which is regarded as more attractive alternative for developing electromagnetic radiation protection products.