Your browser doesn't support javascript.
loading
Metal-Organic-Framework-Derived Carbons: Applications as Solid-Base Catalyst and Support for Pd Nanoparticles in Tandem Catalysis.
Li, Xinle; Zhang, Biying; Fang, Yuhui; Sun, Weijun; Qi, Zhiyuan; Pei, Yuchen; Qi, Shuyan; Yuan, Pengyu; Luan, Xuechen; Goh, Tian Wei; Huang, Wenyu.
Afiliação
  • Li X; Department of Chemistry, Iowa State University, Ames, Iowa, 50011, USA.
  • Zhang B; Ames Laboratory, U.S. Department of Energy, Ames, Iowa, 50011, USA.
  • Fang Y; Department of Chemistry, Iowa State University, Ames, Iowa, 50011, USA.
  • Sun W; Ames Laboratory, U.S. Department of Energy, Ames, Iowa, 50011, USA.
  • Qi Z; Department of Chemistry, Beijing Normal University, Haidian, Beijing, 100875, P. R. China.
  • Pei Y; Department of Chemistry, Iowa State University, Ames, Iowa, 50011, USA.
  • Qi S; Ames Laboratory, U.S. Department of Energy, Ames, Iowa, 50011, USA.
  • Yuan P; Department of Chemistry, Iowa State University, Ames, Iowa, 50011, USA.
  • Luan X; Ames Laboratory, U.S. Department of Energy, Ames, Iowa, 50011, USA.
  • Goh TW; Department of Chemistry, Iowa State University, Ames, Iowa, 50011, USA.
  • Huang W; Ames Laboratory, U.S. Department of Energy, Ames, Iowa, 50011, USA.
Chemistry ; 23(18): 4266-4270, 2017 Mar 28.
Article em En | MEDLINE | ID: mdl-28188655
ABSTRACT
The facile pyrolysis of a bipyridyl metal-organic framework, MOF-253, produces N-doped porous carbons (Cz-MOF-253), which exhibit excellent catalytic activity in the Knoevenagel condensation reaction and outperform other nitrogen-containing MOF-derived carbons. More importantly, by virtue of their high Lewis basicity and porous nature, Cz-MOF-253-supported Pd nanoparticles (Pd/Cz-MOF-253-800) show excellent performance in a one-pot sequential Knoevenagel condensation-hydrogenation reaction.
Palavras-chave

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Chemistry Assunto da revista: QUIMICA Ano de publicação: 2017 Tipo de documento: Article País de afiliação: Estados Unidos

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Chemistry Assunto da revista: QUIMICA Ano de publicação: 2017 Tipo de documento: Article País de afiliação: Estados Unidos