Selective transition-metal-free vicinal cis-dihydroxylation of saturated hydrocarbons.
Chem Sci
; 8(1): 452-457, 2017 Jan 01.
Article
em En
| MEDLINE
| ID: mdl-28451192
ABSTRACT
A transition-metal-free cis-dihydroxylation of saturated hydrocarbons under ambient reaction conditions has been developed. The described approach allows a direct and selective synthesis of vicinal diols. The new reaction thereby proceeds via radical iodination and a sequence of oxidation steps. A broad scope of one-pot dual C(sp3)-H bond functionalization for the selective synthesis of vicinal syn-diols was demonstrated.
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1
Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Chem Sci
Ano de publicação:
2017
Tipo de documento:
Article