Application of black walnut (Juglans nigra) husk for the removal of lead (II) ion from aqueous solution.
Water Sci Technol
; 75(10): 2454-2464, 2017 May.
Article
em En
| MEDLINE
| ID: mdl-28541953
ABSTRACT
The biosorption characteristics of Pb (II) ions from aqueous solution using black walnut (Juglans nigra) seed husk (WSH) biomass were investigated using batch adsorption techniques. The effects of pH, contact time, initial Pb (II) ion concentration, and temperature were studied. The Langmuir, Freundlich and Temkin isotherms were used to analyze the equilibrium data. It was found that the adsorption of Pb (II) ions onto WSH was best described by the Freundlich adsorption model. Biosorption kinetics data were tested using the pseudo-ï¬rst order and pseudo-second order models, and it was observed that the kinetics data fitted the pseudo-second order model. Thermodynamic parameters such as standard Gibbs free energy change (ΔG0), standard enthalpy change (ΔH0) and standard entropy change (ΔS0) were evaluated. The result showed that biosorption of Pb (II) ions onto WSH was spontaneous and endothermic in nature. The FTIR study showed that the following functional groups O-H, C = O, C-O, C-H and N-H were involved in binding Pb (II) ions to the biomass.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Assunto principal:
Poluentes Químicos da Água
/
Purificação da Água
/
Juglans
/
Chumbo
Tipo de estudo:
Prognostic_studies
Idioma:
En
Revista:
Water Sci Technol
Assunto da revista:
SAUDE AMBIENTAL
/
TOXICOLOGIA
Ano de publicação:
2017
Tipo de documento:
Article