Mid-IR spectroscopy of Fe:ZnSe quantum dots.

ABSTRACT

We report spectroscopic characterization of FeZnSe quantum dots (for 2% of Zn/Fe molar ratio) fabricated by microemulsion hydrothermal synthesis. Mid-IR photoluminescence of the 5E↔5T2 transition of Fe2+ ions over 3.5-4.5 µm spectral range was observed in FeZnSe quantum dot samples and kinetics of luminescence have been characterized at temperatures of 30-300 K under direct (2.788 µm) mid-IR excitation and indirect (0.355 µm) photoionization excitation. The radiative lifetime (τrad) was estimated from these measurements to be 48 µs while lifetime at room temperature was measured to be 440 ns. This agrees closely with the behavior of bulk material.