Triple Halide Bridges in Chiral MnII2MnIII6NaI2 Cages: Structural and Magnetic Characterization.
Inorg Chem
; 57(3): 926-929, 2018 Feb 05.
Article
em En
| MEDLINE
| ID: mdl-29368917
ABSTRACT
A family of decanuclear chiral clusters with a MnII2MnIII6NaI2 core have been synthesized from enantiomerically pure Schiff bases. The new systems consist of two MnIIMnIII3NaI units linked by rare triple chloro or bromo bridges between the divalent Mn cations. Susceptibility measurements point out the weak antiferromagnetic interaction mediated by these kinds of bridges and afford the first magnetic measurements for the (µ-Br)3 case.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Inorg Chem
Ano de publicação:
2018
Tipo de documento:
Article
País de afiliação:
Espanha