Stereospecific ß-l-Rhamnopyranosylation through an S<sub>N</sub> i-Type Mechanism by Using Organoboron Reagents.

Nishi, Nobuya; Sueoka, Kazuhiro; Iijima, Kiyoko; Sawa, Ryuichi; Takahashi, Daisuke; Toshima, Kazunobu

Stereospecific ß-l-Rhamnopyranosylation through an S_N i-Type Mechanism by Using Organoboron Reagents.

Nishi, Nobuya; Sueoka, Kazuhiro; Iijima, Kiyoko; Sawa, Ryuichi; Takahashi, Daisuke; Toshima, Kazunobu.

Afiliação

Nishi N; Department of Applied Chemistry, Faculty of Science and Technology, Keio University, 3-14-1 Hiyoshi, Kohoku-ku, Yokohama, 223-8522, Japan.
Sueoka K; Department of Applied Chemistry, Faculty of Science and Technology, Keio University, 3-14-1 Hiyoshi, Kohoku-ku, Yokohama, 223-8522, Japan.
Iijima K; Institute of Microbial Chemistry (BIKAKEN), 3-14-23 Kamiosaki, Shinagawa-ku, Tokyo, 141-0021, Japan.
Sawa R; Institute of Microbial Chemistry (BIKAKEN), 3-14-23 Kamiosaki, Shinagawa-ku, Tokyo, 141-0021, Japan.
Takahashi D; Department of Applied Chemistry, Faculty of Science and Technology, Keio University, 3-14-1 Hiyoshi, Kohoku-ku, Yokohama, 223-8522, Japan.
Toshima K; Department of Applied Chemistry, Faculty of Science and Technology, Keio University, 3-14-1 Hiyoshi, Kohoku-ku, Yokohama, 223-8522, Japan.

Angew Chem Int Ed Engl ; 57(42): 13858-13862, 2018 10 15.

Article em En | MEDLINE | ID: mdl-30098095

Assuntos

Compostos de Boro/química; Compostos Orgânicos/química; Piranos/química; Ramnose/química; Teoria da Densidade Funcional; Glicosilação; Cinética

Palavras-chave

carbohydrates; glycosylation; organoboron reagents; stereoselectivity; ß-l-rhamnosylation

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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Compostos Orgânicos / Piranos / Ramnose / Compostos de Boro Idioma: En Revista: Angew Chem Int Ed Engl Ano de publicação: 2018 Tipo de documento: Article País de afiliação: Japão

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