Realizing the Photoene Reaction with Alkenes under Visible Light Irradiation and Bypassing the Favored [2 + 2]-Photocycloaddition.

Ahuja, Sapna; Raghunathan, Ramya; Kumarasamy, Elango; Jockusch, Steffen; Sivaguru, Jayaraman

Ahuja, Sapna; Raghunathan, Ramya; Kumarasamy, Elango; Jockusch, Steffen; Sivaguru, Jayaraman.

Afiliação

Ahuja S; Center for Photochemical Sciences and Department of Chemistry , Bowling Green State University , Bowling Green , Ohio 43403 , United States.
Raghunathan R; Department of Chemistry , Columbia University , New York , New York 10027 , United States.
Kumarasamy E; Department of Chemistry , Columbia University , New York , New York 10027 , United States.
Jockusch S; Department of Chemistry , Columbia University , New York , New York 10027 , United States.
Sivaguru J; Center for Photochemical Sciences and Department of Chemistry , Bowling Green State University , Bowling Green , Ohio 43403 , United States.

J Am Chem Soc ; 140(41): 13185-13189, 2018 10 17.

Article em En | MEDLINE | ID: mdl-30256105

ABSTRACT

ABSTRACT

The textbook photoreaction between two alkenes is the [2 + 2]-photocycloaddition resulting in functionalized cyclobutanes. Herein, we disclose an unusual reactivity of alkenes that favor photoene reaction over the [2 + 2]-photocycloaddition.

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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: J Am Chem Soc Ano de publicação: 2018 Tipo de documento: Article País de afiliação: Estados Unidos

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