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A Switch in the Hydrophobic/Hydrophilic Gas-Adsorption Character of Prussian Blue Analogues: An Affinity Control for Smart Gas Sorption.
Boudjema, Lotfi; Long, Jérôme; Salles, Fabrice; Larionova, Joulia; Guari, Yannick; Trens, Philippe.
Afiliação
  • Boudjema L; Institut Charles Gerhardt Montpellier, UMR 5253, Matériaux Avancés pour la Catalyse et la Santé, ENSCM/CNRS/UM, 240 Av. Prof. Jeanbrau, 34296, Montpellier Cedex 5, France.
  • Long J; Institut Charles Gerhardt Montpellier, UMR 5253, Ingénierie Moléculaire et Nano-Objets, ENSCM/CNRS/UM, Place E. Bataillon, 34095, Montpellier Cedex 5, France.
  • Salles F; Institut Charles Gerhardt Montpellier, UMR 5253, Agrégats, Interfaces et Matériaux pour l'Energie, ENSCM/CNRS/UM, Place E. Bataillon, 34095, Montpellier Cedex 5, France.
  • Larionova J; Institut Charles Gerhardt Montpellier, UMR 5253, Ingénierie Moléculaire et Nano-Objets, ENSCM/CNRS/UM, Place E. Bataillon, 34095, Montpellier Cedex 5, France.
  • Guari Y; Institut Charles Gerhardt Montpellier, UMR 5253, Ingénierie Moléculaire et Nano-Objets, ENSCM/CNRS/UM, Place E. Bataillon, 34095, Montpellier Cedex 5, France.
  • Trens P; Institut Charles Gerhardt Montpellier, UMR 5253, Matériaux Avancés pour la Catalyse et la Santé, ENSCM/CNRS/UM, 240 Av. Prof. Jeanbrau, 34296, Montpellier Cedex 5, France.
Chemistry ; 25(2): 479-484, 2019 Jan 07.
Article em En | MEDLINE | ID: mdl-30371960
ABSTRACT
Porous coordination polymers are molecule-based materials presenting a high degree of tunability, which offer many advantages for targeted applications over conventional inorganic materials. This work demonstrates that the hydrophilic/hydrophobic character of Prussian blue analogues having a lipophilic feature may be tuned to optimize the gas adsorption properties. The role of the coordinatively unsaturated metal sites is emphasized through a combination of theoretical and experimental study of water, ethanol, and n-hexane adsorption.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Chemistry Assunto da revista: QUIMICA Ano de publicação: 2019 Tipo de documento: Article País de afiliação: França

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Chemistry Assunto da revista: QUIMICA Ano de publicação: 2019 Tipo de documento: Article País de afiliação: França