Facile Synthesis of Unsolvated Alkali Metal Octahydrotriborate Salts MB3 H8 (M=K, Rb, and Cs), Mechanisms of Formation, and the Crystal Structure of KB3 H8.

Chen, Xi-Meng; Ma, Nana; Liu, Xin-Ran; Wei, Changgeng; Cui, Chong-Chao; Cao, Bu-La; Guo, Yanhui; Wang, Lai-Sheng; Gu, Qinfen; Chen, Xuenian

Facile Synthesis of Unsolvated Alkali Metal Octahydrotriborate Salts MB₃ H₈ (M=K, Rb, and Cs), Mechanisms of Formation, and the Crystal Structure of KB₃ H₈.

Chen, Xi-Meng; Ma, Nana; Liu, Xin-Ran; Wei, Changgeng; Cui, Chong-Chao; Cao, Bu-La; Guo, Yanhui; Wang, Lai-Sheng; Gu, Qinfen; Chen, Xuenian.

Afiliação

Chen XM; School of Chemistry and Chemical Engineering, Henan Key Laboratory of Boron Chemistry and Advanced Energy Materials, Henan Normal University, Xinxiang, Henan, 453007, China.
Ma N; School of Chemistry and Chemical Engineering, Henan Key Laboratory of Boron Chemistry and Advanced Energy Materials, Henan Normal University, Xinxiang, Henan, 453007, China.
Liu XR; School of Chemistry and Chemical Engineering, Henan Key Laboratory of Boron Chemistry and Advanced Energy Materials, Henan Normal University, Xinxiang, Henan, 453007, China.
Wei C; School of Chemistry and Chemical Engineering, Henan Key Laboratory of Boron Chemistry and Advanced Energy Materials, Henan Normal University, Xinxiang, Henan, 453007, China.
Cui CC; School of Chemistry and Chemical Engineering, Henan Key Laboratory of Boron Chemistry and Advanced Energy Materials, Henan Normal University, Xinxiang, Henan, 453007, China.
Cao BL; School of Chemistry and Chemical Engineering, Henan Key Laboratory of Boron Chemistry and Advanced Energy Materials, Henan Normal University, Xinxiang, Henan, 453007, China.
Guo Y; Department of Materials Science, Fudan University, Shanghai, 200433, China.
Wang LS; Department of Chemistry, Brown University, Providence, RI, 02912, USA.
Gu Q; Australian Synchrotron (ANSTO), 800 Blackburn Rd, Clayton, 3168, VIC, Australia.
Chen X; School of Chemistry and Chemical Engineering, Henan Key Laboratory of Boron Chemistry and Advanced Energy Materials, Henan Normal University, Xinxiang, Henan, 453007, China.

Angew Chem Int Ed Engl ; 58(9): 2720-2724, 2019 Feb 25.

Article em En | MEDLINE | ID: mdl-30666766

Palavras-chave

X-ray diffraction; alkali metals; boron; nucleophilicity; reaction mechanisms

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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Angew Chem Int Ed Engl Ano de publicação: 2019 Tipo de documento: Article País de afiliação: China

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