A Co-Fe Prussian blue analogue for efficient Fenton-like catalysis: the effect of high-spin cobalt.
Chem Commun (Camb)
; 55(50): 7151-7154, 2019 Jun 25.
Article
em En
| MEDLINE
| ID: mdl-31119224
ABSTRACT
Herein, we, for the first time, report a high spin Co-Fe Prussian blue analogue (Co-Fe PBA) as a highly efficient Fenton-like catalyst for sulfate radical (SO4Ë-) production. Our experiments and density functional theory (DFT) calculations show that the largely elongated SO4-OH bond length, strengthened adsorption and facilitated electron transfer for peroxymonosulfate (PMS) activation catalyzed by high-spin (HS) CoII are the main factors contributing to its excellent activity.
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1
Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Chem Commun (Camb)
Assunto da revista:
QUIMICA
Ano de publicação:
2019
Tipo de documento:
Article
País de afiliação:
China