Iron(II)-Catalyzed Radical Addition to Aldimines with Hantzsch Ester as a Two-Hydrogen Atom Donor.

Tang, Rui; Shao, Ziyan; Wang, Jiancheng; Liu, Zhongxian; Li, Ya-Min; Shen, Yuehai

Tang, Rui; Shao, Ziyan; Wang, Jiancheng; Liu, Zhongxian; Li, Ya-Min; Shen, Yuehai.

Afiliação

Tang R; Faculty of Life Science and Technology , Kunming University of Science and Technology , Kunming 650500 , China.
Shao Z; Faculty of Life Science and Technology , Kunming University of Science and Technology , Kunming 650500 , China.
Wang J; Faculty of Life Science and Technology , Kunming University of Science and Technology , Kunming 650500 , China.
Liu Z; Faculty of Life Science and Technology , Kunming University of Science and Technology , Kunming 650500 , China.
Li YM; Faculty of Life Science and Technology , Kunming University of Science and Technology , Kunming 650500 , China.
Shen Y; Faculty of Life Science and Technology , Kunming University of Science and Technology , Kunming 650500 , China.

J Org Chem ; 84(12): 8177-8184, 2019 06 21.

Article em En | MEDLINE | ID: mdl-31122013

ABSTRACT

ABSTRACT

The first Fe(OTf)2-catalyzed radical addition to aldimines with Hantzsch ester as a two-hydrogen atom donor is reported. The tin-free reaction works well for electron-deficient substrates and provides a potentially useful approach to α-branched amines and α-amino acids.

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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: J Org Chem Ano de publicação: 2019 Tipo de documento: Article País de afiliação: China

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