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Diastereoselective Construction of 2-Aminoindanones via an In(OTf)3-Catalyzed Domino Reaction.
Xing, Siyang; Xia, Hanyu; Guo, Junshuo; Zou, Chenchen; Gao, Tingxuan; Wang, Kui; Zhu, Bolin; Pei, Meiqi; Bai, Mengpei.
Afiliação
  • Xing S; Tianjin Key Laboratory of Structure and Performance for Functional Molecules, Key Laboratory of Inorganic-Organic Hybrid Functional Material Chemistry, Ministry of Education (Tianjin Normal University), College of Chemistry , Tianjin Normal University , Tianjin 300387 , People's Republic of China.
  • Xia H; Tianjin Key Laboratory of Structure and Performance for Functional Molecules, Key Laboratory of Inorganic-Organic Hybrid Functional Material Chemistry, Ministry of Education (Tianjin Normal University), College of Chemistry , Tianjin Normal University , Tianjin 300387 , People's Republic of China.
  • Guo J; Tianjin Key Laboratory of Structure and Performance for Functional Molecules, Key Laboratory of Inorganic-Organic Hybrid Functional Material Chemistry, Ministry of Education (Tianjin Normal University), College of Chemistry , Tianjin Normal University , Tianjin 300387 , People's Republic of China.
  • Zou C; Tianjin Key Laboratory of Structure and Performance for Functional Molecules, Key Laboratory of Inorganic-Organic Hybrid Functional Material Chemistry, Ministry of Education (Tianjin Normal University), College of Chemistry , Tianjin Normal University , Tianjin 300387 , People's Republic of China.
  • Gao T; Tianjin Key Laboratory of Structure and Performance for Functional Molecules, Key Laboratory of Inorganic-Organic Hybrid Functional Material Chemistry, Ministry of Education (Tianjin Normal University), College of Chemistry , Tianjin Normal University , Tianjin 300387 , People's Republic of China.
  • Wang K; Tianjin Key Laboratory of Structure and Performance for Functional Molecules, Key Laboratory of Inorganic-Organic Hybrid Functional Material Chemistry, Ministry of Education (Tianjin Normal University), College of Chemistry , Tianjin Normal University , Tianjin 300387 , People's Republic of China.
  • Zhu B; Tianjin Key Laboratory of Structure and Performance for Functional Molecules, Key Laboratory of Inorganic-Organic Hybrid Functional Material Chemistry, Ministry of Education (Tianjin Normal University), College of Chemistry , Tianjin Normal University , Tianjin 300387 , People's Republic of China.
  • Pei M; Tianjin Key Laboratory of Structure and Performance for Functional Molecules, Key Laboratory of Inorganic-Organic Hybrid Functional Material Chemistry, Ministry of Education (Tianjin Normal University), College of Chemistry , Tianjin Normal University , Tianjin 300387 , People's Republic of China.
  • Bai M; Tianjin Key Laboratory of Structure and Performance for Functional Molecules, Key Laboratory of Inorganic-Organic Hybrid Functional Material Chemistry, Ministry of Education (Tianjin Normal University), College of Chemistry , Tianjin Normal University , Tianjin 300387 , People's Republic of China.
J Org Chem ; 84(14): 8984-8997, 2019 Jul 19.
Article em En | MEDLINE | ID: mdl-31250644
ABSTRACT
An In(OTf)3-catalyzed domino reaction involving sequential oxidative ring opening of aziridines by using the solvent dimethyl sulfoxide and intramolecular Michael addition has been developed for the modular synthesis of 2-aminoindanone compounds by the formation of one new C═O bond and one new C-C bond. The notable feature of this strategy includes broad substrate scope, excellent trans-diastereoselectivities, highly functionalized products, and mild conditions. The catalyst In(OTf)3 plays an important role in the formation of the indanone ring.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: J Org Chem Ano de publicação: 2019 Tipo de documento: Article
Texto completo
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XML
PubMed Links
Buscar no Google

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: J Org Chem Ano de publicação: 2019 Tipo de documento: Article