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Nickel-Catalyzed Chemoselective Acetalization of Aldehydes With Alcohols under Neutral Conditions.
Subaramanian, Murugan; Landge, Vinod G; Mondal, Akash; Gupta, Virendrakumar; Balaraman, Ekambaram.
Afiliação
  • Subaramanian M; Department of Chemistry, Indian Institute of Science Education and Research Tirupati (IISER-Tirupati), Tirupati-, 517507, India.
  • Landge VG; Department of Chemistry, Indian Institute of Science Education and Research Tirupati (IISER-Tirupati), Tirupati-, 517507, India.
  • Mondal A; Department of Chemistry, Indian Institute of Science Education and Research Tirupati (IISER-Tirupati), Tirupati-, 517507, India.
  • Gupta V; Polymer Synthesis & Catalysis, Reliance Research &, Development Centre, Reliance Industries Limited, Ghansoli-, 400701, Navi Mumbai, India.
  • Balaraman E; Department of Chemistry, Indian Institute of Science Education and Research Tirupati (IISER-Tirupati), Tirupati-, 517507, India.
Chem Asian J ; 14(24): 4557-4562, 2019 Dec 13.
Article em En | MEDLINE | ID: mdl-31407487
ABSTRACT
A molecularly defined NiII -complex catalyzing the chemoselective acetalization of aldehydes with alcohols under neutral conditions is reported. The reaction is general, efficient and showed a wide substrate scope (including aliphatic aldehydes) as well as excellent functional group tolerance. Reusability of the present nickel catalyst is also demonstrated.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Chem Asian J Ano de publicação: 2019 Tipo de documento: Article País de afiliação: Índia

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Idioma: En Revista: Chem Asian J Ano de publicação: 2019 Tipo de documento: Article País de afiliação: Índia