Tribological Behavior of Surface-Immobilized Novel Biomimicking Multihierarchical Polymers: The Role of Structure and Surface Attachment.
Langmuir
; 35(48): 15592-15604, 2019 Dec 03.
Article
em En
| MEDLINE
| ID: mdl-31550893
ABSTRACT
The tribological properties of two novel biomimetic multihierarchical polymers, synthesized by covalently linking single bottlebrush polymers onto a hyaluronic acid (HA) backbone, were investigated in the boundary lubrication regime using the surface forces apparatus. The polymers were immobilized on flat substrates, and their lubrication properties and wear resistance were investigated in aqueous media in the absence of a polymer reservoir (i.e., no free polymer chains in the surrounding medium) in order to better reveal the underlying mechanism of surface-attached biomimetic polymers. The effects of composition, structure, and, more particularly, surface attachment (physisorbed vs chemisorbed) on the tribological properties were investigated and compared with other biomimicking systems reported in the literature. The covalently surface attached bottlebrushes allowed wear resistance between sliding surfaces to be significantly improved, compared to physisorbed bottlebrushes, with a constant coefficient of friction (10-1) of up to few tens of MPa. The results confirm that surface-attached bottlebrushes on their own are not responsible for the extremely low friction often reported in the literature or found in articular joints. Moreover, the study confirmed that the irreversible attachment of bottlebrushes, or multihierarchical polymer layers, to surfaces is crucial to improving wear resistance between sliding surfaces in aqueous media.
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01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Langmuir
Assunto da revista:
QUIMICA
Ano de publicação:
2019
Tipo de documento:
Article