The Quasi-Binary Acetonitriletriide Sr3 [C2 N]2.
Angew Chem Int Ed Engl
; 59(1): 339-342, 2020 Jan 02.
Article
em En
| MEDLINE
| ID: mdl-31612543
ABSTRACT
The first quasi-binary acetonitriletriide Sr3 [C2 N]2 has been synthesised and characterised. The nearly colourless crystals were obtained from the reaction of Sr metal, graphite, and elemental N2 , generated by decomposition of Sr(N3 )2 , in a sealed Ni ampoule with the aid of an alkali metal flux. The structure of this compound was analysed via single-crystal X-ray diffraction and the identity of the [C2 N]3- anion was confirmed by Raman spectroscopy and further investigated by quantum-chemical methods. Computed interatomic distances within the [C2 N]3- anion strikingly match the obtained experimental data.
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1
Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Angew Chem Int Ed Engl
Ano de publicação:
2020
Tipo de documento:
Article
País de afiliação:
Alemanha