Ni(COD)(DQ): An Air-Stable 18-Electron Nickel(0)-Olefin Precatalyst.
Angew Chem Int Ed Engl
; 59(19): 7409-7413, 2020 05 04.
Article
em En
| MEDLINE
| ID: mdl-32065839
ABSTRACT
We report that Ni(COD)(DQ) (COD=1,5-cyclooctadiene, DQ=duroquinone), an air-stable 18-electron complex originally described by Schrauzer in 1962, is a competent precatalyst for a variety of nickel-catalyzed synthetic methods from the literature. Due to its apparent stability, use of Ni(COD)(DQ) as a precatalyst allows reactions to be conveniently performed without use of an inert-atmosphere glovebox, as demonstrated across several case studies.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Angew Chem Int Ed Engl
Ano de publicação:
2020
Tipo de documento:
Article
País de afiliação:
Estados Unidos