Biological and Bioinspired Inorganic N-N Bond-Forming Reactions.
Chem Rev
; 120(12): 5252-5307, 2020 06 24.
Article
em En
| MEDLINE
| ID: mdl-32108471
ABSTRACT
The metallobiochemistry underlying the formation of the inorganic N-N-bond-containing molecules nitrous oxide (N2O), dinitrogen (N2), and hydrazine (N2H4) is essential to the lifestyles of diverse organisms. Similar reactions hold promise as means to use N-based fuels as alternative carbon-free energy sources. This review discusses research efforts to understand the mechanisms underlying biological N-N bond formation in primary metabolism and how the associated reactions are tied to energy transduction and organismal survival. These efforts comprise studies of both natural and engineered metalloenzymes as well as synthetic model complexes.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Assunto principal:
Metaloproteínas
/
Nitrogênio
Idioma:
En
Revista:
Chem Rev
Ano de publicação:
2020
Tipo de documento:
Article
País de afiliação:
Estados Unidos