TMEDA in Iron-Catalyzed Hydromagnesiation: Formation of Iron(II)-Alkyl Species for Controlled Reduction to Alkene-Stabilized Iron(0).

Neate, Peter G N; Greenhalgh, Mark D; Brennessel, William W; Thomas, Stephen P; Neidig, Michael L

Neate, Peter G N; Greenhalgh, Mark D; Brennessel, William W; Thomas, Stephen P; Neidig, Michael L.

Afiliação

Neate PGN; Department of Chemistry, University of Rochester, B31 Hutchison Hall, 120 Trustee Road, Rochester, NY, 14627, USA.
Greenhalgh MD; Department of Chemistry, University of Warwick, Coventry, CV4 7AL, UK.
Brennessel WW; Department of Chemistry, University of Rochester, B31 Hutchison Hall, 120 Trustee Road, Rochester, NY, 14627, USA.
Thomas SP; EaStCHEM School of Chemistry, University of Edinburgh, Joseph Black Building, David Brewster Road, Edinburgh, EH9 3FJ, UK.
Neidig ML; Department of Chemistry, University of Rochester, B31 Hutchison Hall, 120 Trustee Road, Rochester, NY, 14627, USA.

Angew Chem Int Ed Engl ; 59(39): 17070-17076, 2020 09 21.

Article em En | MEDLINE | ID: mdl-32542848

Assuntos

Alcenos/química; Etilenodiaminas/química; Compostos Ferrosos/síntese química; Ferro/química; Catálise; Compostos Ferrosos/química; Estrutura Molecular; Oxirredução

Palavras-chave

TMEDA; catalysis; hydromagnesiation; iron; mechanism

Texto completo

Imprimir

XML

PubMed Links

Buscar no Google

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Compostos Ferrosos / Alcenos / Etilenodiaminas / Ferro Idioma: En Revista: Angew Chem Int Ed Engl Ano de publicação: 2020 Tipo de documento: Article País de afiliação: Estados Unidos

Texto completo

Imprimir

XML

PubMed Links

Buscar no Google