Enhanced solid-state plasmon catalyzed oxidation and SERS signal in the presence of transition metal cations at the surface of gold nanostructures.
Phys Chem Chem Phys
; 23(38): 21808-21816, 2021 Oct 06.
Article
em En
| MEDLINE
| ID: mdl-34550121
The effect of several metal cations (Mn2+, Co2+, Ni2+, Cu2+ and Zn2+) on the photochemical conversion of 4-aminothiophenol (4-ATP) into 4,4'-dimercaptoazobenzene (DMAB) is probed using surface enhanced Raman scattering (SERS). The coupling reaction is carried out on the surface of Au nanoparticles and Au nanorods using 532 nm and 632.8 nm laser excitations, respectively, in the absence and presence of metal cations. Here, we report that DMAB formation on the surface of Au nanostructures - when carried out in the solid state - is augmented significantly (by a factor of 1.98 to 4.07 and 3.34 to 5.74 for Au nanoparticle and Au nanorod substrates, respectively, and depending on the metal). Furthermore, the SERS signal is also markedly enhanced. Thus, the results underpin a new way of carrying out a photochemical reaction with a higher yield along with a higher SERS signal.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
Phys Chem Chem Phys
Assunto da revista:
BIOFISICA
/
QUIMICA
Ano de publicação:
2021
Tipo de documento:
Article
País de afiliação:
Índia