Reversible-Addition Fragmentation Chain Transfer Step-Growth Polymerization.
J Am Chem Soc
; 143(39): 15918-15923, 2021 10 06.
Article
em En
| MEDLINE
| ID: mdl-34581557
ABSTRACT
Reversible-addition fragmentation chain transfer (RAFT) polymerization has been widely explored since its discovery due to its structural precision, versatility, and efficiency. However, the lack of tunability of the polymer backbone limits some applications. Herein, we synergistically combine RAFT and step-growth polymerization mechanisms, by employing a highly selective insertion process of a single monomer with a RAFT agent, to achieve RAFT step-growth polymerization. A unique feature of the RAFT step-growth polymers is that each backbone repeat unit bears a pendant RAFT agent, which can subsequently graft side chains in a second polymerization step and afford molecular brush polymers. Enabled by cleavable backbone functionality, we demonstrate transformation of the resulting brushlike polymers into linear chains of uniform size upon a stimulus.
Texto completo:
1
Coleções:
01-internacional
Base de dados:
MEDLINE
Idioma:
En
Revista:
J Am Chem Soc
Ano de publicação:
2021
Tipo de documento:
Article
País de afiliação:
Estados Unidos