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Dienylation of N-benzoylhydrazones with CF3-substituted homoallenylboronates in water.
Ma, Wei-Wei; Yang, Chao; Xie, Qiang; Xu, Yun-He.
Afiliação
  • Ma WW; Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, P. R China. xyh0709@ustc.edu.cn.
  • Yang C; Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, P. R China. xyh0709@ustc.edu.cn.
  • Xie Q; Department of Nuclear Medicine the First Affiliated Hospital of USTC; the Division of Life Sciences and Medicine, University of Science and Technology of China, Hefei, Anhui 230001, P. R China. xieqiang1980@ustc.edu.cn.
  • Xu YH; Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, P. R China. xyh0709@ustc.edu.cn.
Org Biomol Chem ; 20(7): 1386-1390, 2022 02 16.
Article em En | MEDLINE | ID: mdl-35088801
A convenient method for the dienylation of N-benzoylhydrazones in water has been developed. This protocol expanded the synthetic application of functionalized homoallenylboronates to provide the useful 2-aminomethyl-1,3-diene derivatives with high efficiency (up to 99% yield) and stereoselectivity without using any catalyst, additive or inert atmosphere. Furthermore, the transformation of a 2-aminomethyl-1,3-diene derivative to synthesize a functionalized pyrrolidine derivative was also explored.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Água Idioma: En Revista: Org Biomol Chem Assunto da revista: BIOQUIMICA / QUIMICA Ano de publicação: 2022 Tipo de documento: Article
Texto completo
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Água Idioma: En Revista: Org Biomol Chem Assunto da revista: BIOQUIMICA / QUIMICA Ano de publicação: 2022 Tipo de documento: Article