Anomalous Chiral Transfer: Supramolecular Polymerization in a Chiral Medium of a Mesogenic Molecule.
Chem Asian J
; 17(10): e202200223, 2022 May 16.
Article
em En
| MEDLINE
| ID: mdl-35338598
ABSTRACT
Here, we report a medium-to-polymer anomalous chiral transfer in the supramolecular polymerization of a tetraphenylporphyrin-based achiral hydrogen-bonding monomer (TPP) in a chiral medium of 5-cyanobiphenyl CB*. A mixture of TPP in (R)-CB* ([TPP]=7.7â
mol %) at 40 °C gave a columnar oblique LC mesophase, where the individual columns were composed of an optically active helical supramolecular polymer of TPP as a consequence of a successful medium-to-polymer chiral transfer. Meanwhile, upon dilution of CB* with achiral 5-cyanobiphenyl CB, the optical activity of the system showed an anomalous bell-shaped dependency on the composition of CB*/CB, where the gabs value of 0.049 at CB*/CB=50/50 was 6.0â
times larger than the gabs value of CB* alone. Such anomalous chiroptical amplification in CD is most likely due to a change in the stacking geometry of TPP in the oblique columnar LC upon lateral compression.
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Coleções:
01-internacional
Base de dados:
MEDLINE
Assunto principal:
Polímeros
Idioma:
En
Revista:
Chem Asian J
Ano de publicação:
2022
Tipo de documento:
Article
País de afiliação:
Japão