Dynamic Investigation of Battery Materials via Advanced Visualization: From Particle, Electrode to Cell Level.

ABSTRACT

Li-ion batteries, the most-popular secondary battery, are typically electrochemical systems controlled by ion-insertion dynamics. The battery dynamics involve mass transport, charge transfer, ion-electron coupled reactions, electrolyte penetration, ion solvation, and interfacial evolution. However, it is difficult for the traditional electrochemical methods to capture the accurate and individual details of the dynamic processes in "black box" batteries; instead, only the net result of multi-factors on the whole scale. Recently, different advanced visualization techniques have been developed, which provide powerful tools to track and monitor the internal real-time dynamic processes, giving intuitive details and fine information at various scales from crystal lattice, single particle, electrode to cell level. Here, the recent progress on the investigation of electrochemical dynamics in battery materials are reviewed, via developed techniques across wide timescales and space-scales, including the dynamic process inside the active particle, kinetics issues at the electrode/electrolyte interface, dynamic inhomogeneity in the electrode, and dynamic transportation at the cell level. Finally, the fundamental principles to improve the battery dynamics are summarized and new technologies for future more stringent conditions are highlighted. In prospect, this review opens sight on the battery interior for a clearer, deeper, and more thorough understanding of the dynamics.