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Towards Upcycling Biomass-Derived Crosslinked Polymers with Light.
Singathi, Ravichandranath; Raghunathan, Ramya; Krishnan, Retheesh; Kumar Rajendran, Saravana; Baburaj, Sruthy; Sibi, Mukund P; Webster, Dean C; Sivaguru, Jayaraman.
Afiliação
  • Singathi R; Center for Photochemical Science and Department of Chemistry, Bowling Green State University, Bowling Green, OH 43403, USA.
  • Raghunathan R; Center for Photochemical Science and Department of Chemistry, Bowling Green State University, Bowling Green, OH 43403, USA.
  • Krishnan R; Department of Chemistry. Government College for Women, Trivandrum, Kerala, 695014, India.
  • Kumar Rajendran S; School of Advanced Sciences, Chemistry Division, VIT University Chennai Campus, Vandalur-Kelambakkam Road, Chennai, 600127, India.
  • Baburaj S; Center for Photochemical Science and Department of Chemistry, Bowling Green State University, Bowling Green, OH 43403, USA.
  • Sibi MP; Department of Chemistry and Biochemistry, North Dakota State University, Fargo, ND 58108, USA.
  • Webster DC; Department of Coatings and Polymeric Materials, North Dakota State University, Fargo, ND 58108, USA.
  • Sivaguru J; Center for Photochemical Science and Department of Chemistry, Bowling Green State University, Bowling Green, OH 43403, USA.
Angew Chem Int Ed Engl ; 61(31): e202203353, 2022 08 01.
Article em En | MEDLINE | ID: mdl-35545813
ABSTRACT
Photodegradable, recyclable, and renewable, crosslinked polymers from bioresources show promise towards developing a sustainable strategy to address the issue of plastics degradability and recyclability. Photo processes are not widely exploited for upcycling polymers in spite of the potential to have spatial and temporal control of the degradation in addition to being a green process. In this report we highlight a methodology in which biomass-derived crosslinked polymers can be programmed to degrade at ≈300 nm with ≈60 % recovery of the monomer. The recovered monomer was recycled back to the crosslinked polymer.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Plásticos / Polímeros Idioma: En Revista: Angew Chem Int Ed Engl Ano de publicação: 2022 Tipo de documento: Article País de afiliação: Estados Unidos
Texto completo
Imprimir
XML
PubMed Links
Buscar no Google

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Plásticos / Polímeros Idioma: En Revista: Angew Chem Int Ed Engl Ano de publicação: 2022 Tipo de documento: Article País de afiliação: Estados Unidos