Highly efficient Cd(â
¡) removal using 3D N-doped carbon derived from MOFs: Performance and mechanisms.
J Hazard Mater
; 436: 129149, 2022 Aug 15.
Article
em En
| MEDLINE
| ID: mdl-35594671
ABSTRACT
Cadmium (Cd) removal is imperative to ensure the safety of aquatic-ecosystem, yet its effective removal technology has remained elusive by far. To address this concern, three-dimensional N-doped carbon (NC) polyhedrons affording ample porosity is fabricated based upon the thermal carbonization and KOH activation of zeolitic imidazolate framework-8 (ZIF-8) precursor. Thus-derived activated NC (a-NC) adsorbent not only overcomes the inherent instability of ZIF-8 but also harvests a maximum Cd(â
¡) adsorption capacity of 370.2 mg g-1, which evidently surpasses those of bare NC counterpart as well as previously reported adsorbents. Impressively, a-NC achieves ca. 100% removal of aqueous Cd(â
¡) in a broad working pH range (5-9), and particularly attains stable performances (81-92%) in various realistic water. Theoretical calculations in combination with experimental characterizations further offer mechanistic insight into the enhanced removal exerted by a-NC. Notably, owing to the increased specific surface area (3041 vs. 389 m2 g-1) and enhanced sp2 carbon content (91.7 vs. 68.8%) of a-NC as compared to NC, advanced Cd(â
¡) adsorption via a-NC can be exhibited. Our designed a-NC material harnessing favorable recycling capability would be in particular attractive in the realm of practical Cd(â
¡) remediation.
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01-internacional
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MEDLINE
Idioma:
En
Revista:
J Hazard Mater
Assunto da revista:
SAUDE AMBIENTAL
Ano de publicação:
2022
Tipo de documento:
Article