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A Molecular "A-Type" Tangled Metallocube.
Ma, Li-Li; Li, Yang; Li, Xin; Zhang, Le; Sun, Li-Ying; Han, Ying-Feng.
Afiliação
  • Ma LL; Key Laboratory of Synthetic and Natural Functional Molecule of the Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi'an, 710127, P. R. China.
  • Li Y; Key Laboratory of Synthetic and Natural Functional Molecule of the Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi'an, 710127, P. R. China.
  • Li X; Key Laboratory of Synthetic and Natural Functional Molecule of the Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi'an, 710127, P. R. China.
  • Zhang L; Key Laboratory of Synthetic and Natural Functional Molecule of the Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi'an, 710127, P. R. China.
  • Sun LY; Key Laboratory of Synthetic and Natural Functional Molecule of the Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi'an, 710127, P. R. China.
  • Han YF; Key Laboratory of Synthetic and Natural Functional Molecule of the Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi'an, 710127, P. R. China.
Angew Chem Int Ed Engl ; 61(35): e202208376, 2022 08 26.
Article em En | MEDLINE | ID: mdl-35796291
ABSTRACT
Tangled cubes feature the topology of typical Platonic cubes, with their "faces" traversed by edges in different ways. This study generates an "A-type" tangled metallocube from the reaction of binuclear gold-NHC complex and H2 S. The tangled cube topology was validated by multinuclear nuclear magnetic resonance (NMR) spectroscopy, high-resolution electrospray-ionization (HR-ESI) mass spectrometry, and single-crystal X-ray diffraction analysis. This study offers a simple and effective approach to designing and fabricating new, topologically unique molecular structures.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Espectrometria de Massas por Ionização por Electrospray / Ouro Idioma: En Revista: Angew Chem Int Ed Engl Ano de publicação: 2022 Tipo de documento: Article
Texto completo
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Assunto principal: Espectrometria de Massas por Ionização por Electrospray / Ouro Idioma: En Revista: Angew Chem Int Ed Engl Ano de publicação: 2022 Tipo de documento: Article