A Molecular "A-Type" Tangled Metallocube.
Angew Chem Int Ed Engl
; 61(35): e202208376, 2022 08 26.
Article
em En
| MEDLINE
| ID: mdl-35796291
ABSTRACT
Tangled cubes feature the topology of typical Platonic cubes, with their "faces" traversed by edges in different ways. This study generates an "A-type" tangled metallocube from the reaction of binuclear gold-NHC complex and H2 S. The tangled cube topology was validated by multinuclear nuclear magnetic resonance (NMR) spectroscopy, high-resolution electrospray-ionization (HR-ESI) mass spectrometry, and single-crystal X-ray diffraction analysis. This study offers a simple and effective approach to designing and fabricating new, topologically unique molecular structures.
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1
Coleções:
01-internacional
Base de dados:
MEDLINE
Assunto principal:
Espectrometria de Massas por Ionização por Electrospray
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Ouro
Idioma:
En
Revista:
Angew Chem Int Ed Engl
Ano de publicação:
2022
Tipo de documento:
Article