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The polychloromethylation/acyloxylation of 1,6-enynes with chloroalkanes and diacyl peroxides through dual-role designs.
Zhang, Jun-Hao; Jiang, Li-Lin; Hu, Sen-Jie; Li, Jiao-Zhe; Yu, Xuan-Chi; Liu, Fa-Liang; Guan, Yu-Tao; Lei, Ke-Wei; Wei, Wen-Ting.
Afiliação
  • Zhang JH; School of Materials Science and Chemical Engineering, Ningbo University, Ningbo, Zhejiang, 315211, China. weiwenting@nbu.edu.cn.
  • Jiang LL; School of Materials Science and Chemical Engineering, Ningbo University, Ningbo, Zhejiang, 315211, China. weiwenting@nbu.edu.cn.
  • Hu SJ; School of Materials Science and Chemical Engineering, Ningbo University, Ningbo, Zhejiang, 315211, China. weiwenting@nbu.edu.cn.
  • Li JZ; School of Materials Science and Chemical Engineering, Ningbo University, Ningbo, Zhejiang, 315211, China. weiwenting@nbu.edu.cn.
  • Yu XC; School of Materials Science and Chemical Engineering, Ningbo University, Ningbo, Zhejiang, 315211, China. weiwenting@nbu.edu.cn.
  • Liu FL; School of Materials Science and Chemical Engineering, Ningbo University, Ningbo, Zhejiang, 315211, China. weiwenting@nbu.edu.cn.
  • Guan YT; School of Materials Science and Chemical Engineering, Ningbo University, Ningbo, Zhejiang, 315211, China. weiwenting@nbu.edu.cn.
  • Lei KW; School of Materials Science and Chemical Engineering, Ningbo University, Ningbo, Zhejiang, 315211, China. weiwenting@nbu.edu.cn.
  • Wei WT; School of Materials Science and Chemical Engineering, Ningbo University, Ningbo, Zhejiang, 315211, China. weiwenting@nbu.edu.cn.
Org Biomol Chem ; 20(35): 7067-7070, 2022 Sep 14.
Article em En | MEDLINE | ID: mdl-35993972
ABSTRACT
The novel polychloromethylation/acyloxylation of 1,6-enynes with chloroalkanes and diacyl peroxides through dual-role designs has been developed to prepare 2-pyrrolidinone derivatives with polychloromethyl units with the use of an inexpensive copper salt under mild conditions. This strategy includes two dual-role designs, not only improving atomic utilization but also allowing a cleaner process. The wide substrate scope and simple reaction conditions demonstrate the practicability of this protocol.
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Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Tipo de estudo: Guideline Idioma: En Revista: Org Biomol Chem Assunto da revista: BIOQUIMICA / QUIMICA Ano de publicação: 2022 Tipo de documento: Article País de afiliação: China
Texto completo
Imprimir
XML
PubMed Links
Buscar no Google

Texto completo: 1 Coleções: 01-internacional Base de dados: MEDLINE Tipo de estudo: Guideline Idioma: En Revista: Org Biomol Chem Assunto da revista: BIOQUIMICA / QUIMICA Ano de publicação: 2022 Tipo de documento: Article País de afiliação: China